Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000472569> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W2000472569 endingPage "2049" @default.
- W2000472569 startingPage "2039" @default.
- W2000472569 abstract "Sugars possessing the arabino (2,3,4-trans,cis) configuration exist as furanoses to a greater extent in dimethyl sulfoxide than in water. Their 2,3-di-O-methyl derivatives show an even stronger preference for a five membered ring structure in both solvents. This is most marked for 2,3-di-O-methyl-D-arabinose and 2,3-di-O-methyl-D-altrose, which are 65% and 80% furanose, respectively, in dimethyl sulfoxide. Compounds in the xylo (2,3,4-trans,trans) or lyxo (2,3,4-cis,trans) series show little tendency to be furanoses in either solvent. However, α-pyranoses in the lyxo series are relatively more stable in dimethyl sulfoxide than in water, whereas the anomeric composition for members of the xylo series is the same in both solvents. Some of these variations in the equilibria are attributed to the preferential stabilization of pyranose forms in water. D-Lyxose and D-ribose show nuclear magnetic resonance spectral differences in the two solvents that appear to be due to conformational, as well as tautomeric, equilibrium changes.An equatorial anomeric hydroxyl proton of a given pair in dimethyl sulfoxide shows a larger spacing (6.5–8.0 c.p.s.) than an axial anomeric hydroxyl proton (4–5 c.p.s.). The signal for the latter proton occurs at higher field than an equatorial OH-1, except when OH-2 is axial." @default.
- W2000472569 created "2016-06-24" @default.
- W2000472569 creator A5032968348 @default.
- W2000472569 creator A5051466871 @default.
- W2000472569 date "1966-09-01" @default.
- W2000472569 modified "2023-09-27" @default.
- W2000472569 title "PYRANOSE–FURANOSE AND ANOMERIC EQUILIBRIA: INFLUENCE OF SOLVENT AND OF PARTIAL METHYLATION" @default.
- W2000472569 cites W1515693717 @default.
- W2000472569 cites W1928150933 @default.
- W2000472569 cites W1968960082 @default.
- W2000472569 cites W1976590772 @default.
- W2000472569 cites W2027727419 @default.
- W2000472569 cites W2028238751 @default.
- W2000472569 cites W2061899553 @default.
- W2000472569 cites W2078088448 @default.
- W2000472569 cites W2314209983 @default.
- W2000472569 cites W2325462638 @default.
- W2000472569 cites W2326068861 @default.
- W2000472569 cites W2334414742 @default.
- W2000472569 doi "https://doi.org/10.1139/v66-304" @default.
- W2000472569 hasPublicationYear "1966" @default.
- W2000472569 type Work @default.
- W2000472569 sameAs 2000472569 @default.
- W2000472569 citedByCount "70" @default.
- W2000472569 countsByYear W20004725692012 @default.
- W2000472569 countsByYear W20004725692014 @default.
- W2000472569 countsByYear W20004725692015 @default.
- W2000472569 countsByYear W20004725692017 @default.
- W2000472569 countsByYear W20004725692018 @default.
- W2000472569 countsByYear W20004725692019 @default.
- W2000472569 countsByYear W20004725692020 @default.
- W2000472569 countsByYear W20004725692021 @default.
- W2000472569 countsByYear W20004725692022 @default.
- W2000472569 crossrefType "journal-article" @default.
- W2000472569 hasAuthorship W2000472569A5032968348 @default.
- W2000472569 hasAuthorship W2000472569A5051466871 @default.
- W2000472569 hasBestOaLocation W20004725691 @default.
- W2000472569 hasConcept C111233374 @default.
- W2000472569 hasConcept C155647269 @default.
- W2000472569 hasConcept C173985810 @default.
- W2000472569 hasConcept C178790620 @default.
- W2000472569 hasConcept C185592680 @default.
- W2000472569 hasConcept C191423414 @default.
- W2000472569 hasConcept C2778448320 @default.
- W2000472569 hasConcept C2778452553 @default.
- W2000472569 hasConcept C2780378348 @default.
- W2000472569 hasConcept C2780471494 @default.
- W2000472569 hasConcept C34490408 @default.
- W2000472569 hasConcept C71240020 @default.
- W2000472569 hasConcept C7947691 @default.
- W2000472569 hasConceptScore W2000472569C111233374 @default.
- W2000472569 hasConceptScore W2000472569C155647269 @default.
- W2000472569 hasConceptScore W2000472569C173985810 @default.
- W2000472569 hasConceptScore W2000472569C178790620 @default.
- W2000472569 hasConceptScore W2000472569C185592680 @default.
- W2000472569 hasConceptScore W2000472569C191423414 @default.
- W2000472569 hasConceptScore W2000472569C2778448320 @default.
- W2000472569 hasConceptScore W2000472569C2778452553 @default.
- W2000472569 hasConceptScore W2000472569C2780378348 @default.
- W2000472569 hasConceptScore W2000472569C2780471494 @default.
- W2000472569 hasConceptScore W2000472569C34490408 @default.
- W2000472569 hasConceptScore W2000472569C71240020 @default.
- W2000472569 hasConceptScore W2000472569C7947691 @default.
- W2000472569 hasIssue "17" @default.
- W2000472569 hasLocation W20004725691 @default.
- W2000472569 hasOpenAccess W2000472569 @default.
- W2000472569 hasPrimaryLocation W20004725691 @default.
- W2000472569 hasRelatedWork W1971078066 @default.
- W2000472569 hasRelatedWork W1975914784 @default.
- W2000472569 hasRelatedWork W1987162978 @default.
- W2000472569 hasRelatedWork W1997986587 @default.
- W2000472569 hasRelatedWork W2000472569 @default.
- W2000472569 hasRelatedWork W2009328128 @default.
- W2000472569 hasRelatedWork W2029488394 @default.
- W2000472569 hasRelatedWork W2053586833 @default.
- W2000472569 hasRelatedWork W2119425614 @default.
- W2000472569 hasRelatedWork W2945132211 @default.
- W2000472569 hasVolume "44" @default.
- W2000472569 isParatext "false" @default.
- W2000472569 isRetracted "false" @default.
- W2000472569 magId "2000472569" @default.
- W2000472569 workType "article" @default.