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- W2000473760 abstract "This paper introduces a fundamentally new concept in adsorbents, whereby the sorption of an aqueous solute by a cross-linked polymer is controlled by a gel to liquid-crystalline phase transition. To demonstrate proof of principle, a bilayer forming surfactant, N,N-dioctadecyl,N,N-dimethylammonium bromide (DODAB) has been immobilized onto a cation exchange resin, Dowex 50WX2, and its thermotropic phase behavior and solute-adsorption properties have been investigated. Examination by a combination of differential scanning calorimetry and X-ray scattering has confirmed the retention of a gel to liquid-crystalline phase transition of the surfactant, occurring between 296 and 318 K. Adsorption measurements that were made for 4-chlorotetrahydropyran, 1,2-dichloroethane, and benzyl alcohol have also confirmed uptake by the resin in the liquid-crystalline phase and release in the gel phase." @default.
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- W2000473760 date "2007-04-06" @default.
- W2000473760 modified "2023-09-25" @default.
- W2000473760 title "Self-Cleaning Resins" @default.
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- W2000473760 doi "https://doi.org/10.1021/ja068679f" @default.
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