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- W2000474583 abstract "Positive-ion mass spectra of four clinically important drugs of low volatility (amoxicillin, M.W. 365; daunorubicin, M.W. 527; erythromycin, M.W. 733; and digoxin, M.W. 780) have been generated via field desorption with a double-focussing magnetic sector instrument (FD/MS) and via pulsed CO2 laser desorption/ionization with a Fourier transform ion cyclotron resonance mass spectrometer (LD/FT/ICR). LD/FT/ICR based upon a single laser pulse produces a pseudomolecular ion of comparable (erythromycin, daunorubicin) or greater (amoxicillin, digoxin) relative abundance than FD/MS or fast atom bombardment (FAB/MS). LD/FT/ICR also offers routinely high mass accuracy (e.g. to within ±0.003 u for the mass range 404–819 u, no sample derivatization, and minimal sample preparation." @default.
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- W2000474583 date "1986-10-01" @default.
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- W2000474583 title "Laser desorption/Fourier transform ion cyclotron resonance vs. field desorption/magnetic sector mass spectrometry. Erythromycin, amoxicillin, digoxin, and daunorubicin" @default.
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- W2000474583 doi "https://doi.org/10.1016/0168-1176(86)85047-9" @default.
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