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- W2000474769 abstract "Abstract We report the synthesis and characterization of cobalt(II) complexes with two macrocyclic Schiff base ligands, 5,7,7,12,14,14-hexamethyl-1,4,8,11,-tetraazacyclotetradeca-4,11-diene(Me6 [14]4,11-dieneN4) and 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,14-diene(Me6 [14]4,14-dieneN4), containing a large variety of axial ligands. The complexes are low spin and predominantly five-coordinate, the d–d electronic spectra and electron paramagnetic resonance (epr) spectra being consistent with a square pyramidal ligand environment. The complex [Co(Me6 [14] 4,11-dieneN4)] (ClO4)2 functions as a reversible oxygen carrier in several solvents and in the presence of several Lewis bases. Formation of the oxygen adduct in N, N-dimethylformamide (DMF) has been studied spectrophotometrically and by means of epr." @default.
- W2000474769 created "2016-06-24" @default.
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- W2000474769 date "1977-10-01" @default.
- W2000474769 modified "2023-10-14" @default.
- W2000474769 title "FIVE-COORDINATE COBALT(II) COMPLEXES OF MACROCYCLIC LIGANDS — A NEW REVERSIBLE OXYGEN CARRYING SYSTEM" @default.
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- W2000474769 doi "https://doi.org/10.1080/00958977708073045" @default.
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