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- W2000474810 abstract "Four coordination polymers, [Cu(4-dpyh)0.5(1,2-BDC)(H2O)3]·H2O (1), [Cu(4-dpyh)(1,3-BDC)(H2O)] (2), [Cd(3-dpyh)0.5(1,3-BDC)(H2O)2]·H2O (3), and [Zn(3-dpyh)(1,3-BDC)]·3H2O (4) [4-dpyh = N,N′-bis(4-pyridinecarboxamide)-1,6-hexane, 3-dpyh = N,N′-bis(3-pyridinecarboxamide)-1,6-hexane, 1,2-H2BDC = 1,2-benzenedicarboxylic acid and 1,3-H2BDC = 1,3-benzenedicarboxylic acid], have been hydrothermally synthesized. X-ray diffraction analyses reveal that 1 is a discrete [Cu2(4-dpyh)(1,2-BDC)2] dinuclear structure. Compound 2 exhibits a 2-D grid layer constructed from 1-D linear [Cu(1,3-BDC)]n chains and [Cu(4-dpyh)]n chains. Compound 3 features a 1-D ladder-like chain formed by the 1-D linear [Cd(1,3-BDC)]n chains and 3-dpyh bridging ligands. Compound 4 displays a 2-D undulated layer containing meso-helical [Zn(3-dpyh)]n chains and linear [Zn(1,3-BDC)]n chains. The neighboring dinuclear complexes for 1, adjacent chains for 3, and adjacent layers for 2 and 4 are further linked by hydrogen bonding interactions to form 2-D (for 1) or 3-D supramolecular networks (for 2–4). The influences of the different dicarboxylates and metal on the structures of 1–4 have been discussed. The electrochemical behaviors of 1 and 2, the thermal stabilities and fluorescent properties of 1–4, and the fluorescent selectivities of 3 and 4 have been investigated." @default.
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- W2000474810 date "2014-11-26" @default.
- W2000474810 modified "2023-09-23" @default.
- W2000474810 title "Assembly and properties of four new metal–organic coordination polymers with flexible bis-pyridyl-bis-amide ligands: effect of aromatic dicarboxylates and central metal ions on the structures" @default.
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- W2000474810 doi "https://doi.org/10.1080/00958972.2014.983492" @default.
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