FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000476464> ?p ?o ?g. }

• W2000476464 abstract "The reactions between nitrogen dioxide (NO2) and conjugated dienes in the urban atmosphere may contribute to elevated atmospheric NO2 concentrations in winter pollution episodes. In response to a need for kinetic data for these reactions, a simple method for predicting rate constants for the reaction between nitrogen dioxide (NO2) and alkyl-substituted alkenes (monoalkenes and conjugated dienes) has been developed. A structure–activity relationship (SAR) based on the structure of the alkene is shown to be useful in providing an initial estimate of an unknown rate constant for such reactions. The SAR is formulated using rate constants predicted by a correlation between the logarithm of an experimentally determined rate constant and the calculated energy of the highest occupied molecular orbital (HOMO) of the alkene under consideration. The success of the approach is judged by the probabilitythat the rate constant predicted by the SAR lies within a factor of two of the measured value for those monoalkenes and dienes for which experimental data exist. These probabilities were 82% for the dienes, but only 43% for the monoalkenes. However, rate constants for 94% of the dienes and 86% of the monoalkenes were predicted within a factor of three. For the dienes, at least, the SAR thus provides a good chance of providing a first estimate of the rate constant for cases where experiments have not yet been performed." @default.
• W2000476464 created "2016-06-24" @default.
• W2000476464 creator A5027161191 @default.
• W2000476464 creator A5027345031 @default.
• W2000476464 creator A5041721477 @default.
• W2000476464 date "2002-01-21" @default.
• W2000476464 modified "2023-09-25" @default.
• W2000476464 title "A structure–activity relationship (SAR) for predicting rate constants for the reaction of nitrogen dioxide (NO2) with alkenes" @default.
• W2000476464 cites W1488932668 @default.
• W2000476464 cites W1967516078 @default.
• W2000476464 cites W1969171521 @default.
• W2000476464 cites W1975575924 @default.
• W2000476464 cites W1982059545 @default.
• W2000476464 cites W1984289546 @default.
• W2000476464 cites W2007770371 @default.
• W2000476464 cites W2011084605 @default.
• W2000476464 cites W2014799094 @default.
• W2000476464 cites W2031207279 @default.
• W2000476464 cites W2032624599 @default.
• W2000476464 cites W2034270729 @default.
• W2000476464 cites W2046291059 @default.
• W2000476464 cites W2046680750 @default.
• W2000476464 cites W2046994821 @default.
• W2000476464 cites W2047192620 @default.
• W2000476464 cites W2049571850 @default.
• W2000476464 cites W2051215171 @default.
• W2000476464 cites W2054427495 @default.
• W2000476464 cites W2080736820 @default.
• W2000476464 cites W2083425072 @default.
• W2000476464 cites W2089642731 @default.
• W2000476464 cites W2093204787 @default.
• W2000476464 cites W2102595784 @default.
• W2000476464 cites W2117340539 @default.
• W2000476464 cites W2127336290 @default.
• W2000476464 cites W2155358697 @default.
• W2000476464 cites W2951121457 @default.
• W2000476464 doi "https://doi.org/10.1039/b106965a" @default.
• W2000476464 hasPublicationYear "2002" @default.
• W2000476464 type Work @default.
• W2000476464 sameAs 2000476464 @default.
• W2000476464 citedByCount "1" @default.
• W2000476464 crossrefType "journal-article" @default.
• W2000476464 hasAuthorship W2000476464A5027161191 @default.
• W2000476464 hasAuthorship W2000476464A5027345031 @default.
• W2000476464 hasAuthorship W2000476464A5041721477 @default.
• W2000476464 hasConcept C112613896 @default.
• W2000476464 hasConcept C121332964 @default.
• W2000476464 hasConcept C134306372 @default.
• W2000476464 hasConcept C135889238 @default.
• W2000476464 hasConcept C147597530 @default.
• W2000476464 hasConcept C147789679 @default.
• W2000476464 hasConcept C148898269 @default.
• W2000476464 hasConcept C161790260 @default.
• W2000476464 hasConcept C175113610 @default.
• W2000476464 hasConcept C178790620 @default.
• W2000476464 hasConcept C185592680 @default.
• W2000476464 hasConcept C199360897 @default.
• W2000476464 hasConcept C2776254738 @default.
• W2000476464 hasConcept C2777027219 @default.
• W2000476464 hasConcept C2780263894 @default.
• W2000476464 hasConcept C2780723490 @default.
• W2000476464 hasConcept C33923547 @default.
• W2000476464 hasConcept C39927690 @default.
• W2000476464 hasConcept C41008148 @default.
• W2000476464 hasConcept C521977710 @default.
• W2000476464 hasConcept C537208039 @default.
• W2000476464 hasConcept C62520636 @default.
• W2000476464 hasConcept C65440619 @default.
• W2000476464 hasConcept C93391505 @default.
• W2000476464 hasConcept C97355855 @default.
• W2000476464 hasConceptScore W2000476464C112613896 @default.
• W2000476464 hasConceptScore W2000476464C121332964 @default.
• W2000476464 hasConceptScore W2000476464C134306372 @default.
• W2000476464 hasConceptScore W2000476464C135889238 @default.
• W2000476464 hasConceptScore W2000476464C147597530 @default.
• W2000476464 hasConceptScore W2000476464C147789679 @default.
• W2000476464 hasConceptScore W2000476464C148898269 @default.
• W2000476464 hasConceptScore W2000476464C161790260 @default.
• W2000476464 hasConceptScore W2000476464C175113610 @default.
• W2000476464 hasConceptScore W2000476464C178790620 @default.
• W2000476464 hasConceptScore W2000476464C185592680 @default.
• W2000476464 hasConceptScore W2000476464C199360897 @default.
• W2000476464 hasConceptScore W2000476464C2776254738 @default.
• W2000476464 hasConceptScore W2000476464C2777027219 @default.
• W2000476464 hasConceptScore W2000476464C2780263894 @default.
• W2000476464 hasConceptScore W2000476464C2780723490 @default.
• W2000476464 hasConceptScore W2000476464C33923547 @default.
• W2000476464 hasConceptScore W2000476464C39927690 @default.
• W2000476464 hasConceptScore W2000476464C41008148 @default.
• W2000476464 hasConceptScore W2000476464C521977710 @default.
• W2000476464 hasConceptScore W2000476464C537208039 @default.
• W2000476464 hasConceptScore W2000476464C62520636 @default.
• W2000476464 hasConceptScore W2000476464C65440619 @default.
• W2000476464 hasConceptScore W2000476464C93391505 @default.
• W2000476464 hasConceptScore W2000476464C97355855 @default.
• W2000476464 hasLocation W20004764641 @default.
• W2000476464 hasOpenAccess W2000476464 @default.
• W2000476464 hasPrimaryLocation W20004764641 @default.
• W2000476464 hasRelatedWork W1570157435 @default.
• W2000476464 hasRelatedWork W1907226147 @default.

• next