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• W2000480295 abstract "Abstract Polysiloxane–polyester copolymers have been synthesized for the first time by direct polycondensation of a series of diacids (butanedioic, hexanedioic, and octanedioic acid) and α,ω‐bis(3‐hydroxypropyl) polydimethylsiloxanes catalyzed with Novozyme‐435 in high yields (>90%) without the cleavage of SiO bonds. The effects of monomer chain length, reaction temperature, and water removal method on the number–average molecular weight ( M n ) of the resulted copolymers were investigated. Thermogravimetric and differential scanning calorimetry analyses indicated that the produced copolymer was more thermally stable than poly(1,8‐octyladipate) and the T g was lowered to −111°C. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008" @default.
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• W2000480295 date "2008-01-29" @default.
• W2000480295 modified "2023-10-18" @default.
• W2000480295 title "Synthesis of polysiloxane–polyester copolymer by lipase-catalyzed polycondensation" @default.
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• W2000480295 doi "https://doi.org/10.1002/app.27807" @default.
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