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- W2000481477 abstract "Abstract In mixtures of spherical molecules component B is replaced by dumbbell-like molecules with potential parameters chosen such that the bubble density and the vapor pressure of pure component B remain the same. The excess properties gE, hE, and vE are calculated by a Weeks—Chandler3Āndersen type perturbation theory for several energy-ratios, size-ratios and elongations of the molecules. It is found that starting from spherical molecules of equal size the gE and hE-values become more negative with increasing elongation. The opposite occurs if the B-molecules have a volume larger than the other ones by a factor of about 2. It is argued that these shape effects can roughly be incorporated into the kAB-parameter which then for molecules not too different in size will be negative." @default.
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- W2000481477 date "1989-11-01" @default.
- W2000481477 modified "2023-09-27" @default.
- W2000481477 title "Effect of molecular shape on liquid mixture excess properties" @default.
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- W2000481477 doi "https://doi.org/10.1016/0378-3812(89)80368-1" @default.
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