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- W2000484306 abstract "The molecular structure of (2,2′-bipyridine)dimesitylplatinum as determined by X-ray diffraction reveals efficient protection of the axial positions of the essentially square-planar platinum(II) centre. The chemical consequences include a strongly diminished propensity towards oxidative addition and the electrochemically reversible oxidation at about +0.4 V vs. Fc/Fc+ to a reactive PtIII cation. In conjunction with the MLCT absorption and emission energies and the potential for reversible reduction to an anion radical complex, the contributions from intra- and intermolecular reorganisation could be reliably determined. Die röntgendiffraktrometrisch bestimmte Molekülstruktur von (2,2′-Bipyridin)dimesitylplatin lässt eine effektive Abschirmung der axialen Positionen des im wesentlichen quadratisch planar konfigurierten Platin(II)-Zentrums erkennen. Zu den chemischen Konsequenzen hieraus zählen eine starke Zurückdrängung oxidativer Additionsreaktionen sowie die elektrochemisch reversible Oxidation zu einem reaktiven PtIII-Kation bei ca. +0.4 V gegen Ferrocen. Zusammen mit den MLCT-Absorptions- und Emissionsenergien sowie dem Potential für reversible Reduktion zu einem Radikalanionkomplex lassen sich so die Beiträge für intra- und intermolekulare Reorganisation zuverlässig bestimmen." @default.
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- W2000484306 date "1992-11-01" @default.
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- W2000484306 title "Axiale abschirmung des quadratisch-planar konfigurierten platin(II) in strukturell charakterisiertem (bpy)PtMes2: Lumineszenz und elektrochemisch reversible Bildung von Platin(III)" @default.
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- W2000484306 doi "https://doi.org/10.1016/0022-328x(92)83497-6" @default.
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