FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000485959> ?p ?o ?g. }

• W2000485959 endingPage "9674" @default.
• W2000485959 startingPage "9665" @default.
• W2000485959 abstract "Herein, we describe the synthesis and characterization of a novel series of single-tail amphiphiles LPyCn (Py=pyridine, Cn=C18, C16, C14, C10) and their copper(II)-containing complexes, which are of relevance for patterned films. The N-(pyridine-2-ylmethyl)alkyl-1-amine ligands and their complexes [CuIICl2(LPyC18)] (1), [CuIICl2(LPyC16)] (2), [CuIICl2(LPyC14)] (3), [CuIIBr2(LPyC18)] (4), [CuIIBr2(LPyC16)] (5), and [CuIIBr2(LPyC10)] (6) were synthesized, isolated, and characterized by means of mass spectrometry, IR and NMR spectroscopies, and elemental analysis. Complexes 1, 2, 3, and 6 had their molecular structure solved by X-ray diffraction methods, which showed that the local geometry around the metal center is distorted square planar. With the aim of using these species as precursors for redox-responsive films, an assessment of their electrochemical properties involved cyclic voltammetry in different solvents, with different supporting electrolytes and scan rates. Density functional theory calculations of relevant species in bulk and at interfaces were used to evaluate their electronic structure and dipole moments. The morphology and order of the resulting films at the air/water interface were studied by isothermal compression and Brewster angle microscopy. Biphasic patterned Langmuir films were observed for all complexes except 3 and 6, and dependence on the chain length and the nature of the halogen coligand determine the characteristics of the isotherms and their intricate topology. Complexes 3 and 6, which have shorter chain lengths, failed to exhibit organization. These results exemplify the first comprehensive study of the behavior of single-tail metallosurfactants, which are likely to lead to high-end technological applications based on their patterned films." @default.
• W2000485959 created "2016-06-24" @default.
• W2000485959 creator A5013652065 @default.
• W2000485959 creator A5027672816 @default.
• W2000485959 creator A5033107754 @default.
• W2000485959 creator A5047735009 @default.
• W2000485959 creator A5047963541 @default.
• W2000485959 creator A5075941140 @default.
• W2000485959 date "2008-10-21" @default.
• W2000485959 modified "2023-10-12" @default.
• W2000485959 title "Interfacial Behavior and Film Patterning of Redox‐Active Cationic Copper(II)‐Containing Surfactants" @default.
• W2000485959 cites W1486182524 @default.
• W2000485959 cites W1670746996 @default.
• W2000485959 cites W1967244854 @default.
• W2000485959 cites W1971378526 @default.
• W2000485959 cites W1971944253 @default.
• W2000485959 cites W1973070680 @default.
• W2000485959 cites W1973782611 @default.
• W2000485959 cites W1982009948 @default.
• W2000485959 cites W1983050331 @default.
• W2000485959 cites W1984888786 @default.
• W2000485959 cites W1994221195 @default.
• W2000485959 cites W2000738604 @default.
• W2000485959 cites W2004441338 @default.
• W2000485959 cites W2006622554 @default.
• W2000485959 cites W2009590153 @default.
• W2000485959 cites W2015406003 @default.
• W2000485959 cites W2016089121 @default.
• W2000485959 cites W2019796506 @default.
• W2000485959 cites W2023271753 @default.
• W2000485959 cites W2025130425 @default.
• W2000485959 cites W2025457908 @default.
• W2000485959 cites W2034341880 @default.
• W2000485959 cites W2036037731 @default.
• W2000485959 cites W2036537138 @default.
• W2000485959 cites W2040338073 @default.
• W2000485959 cites W2043410034 @default.
• W2000485959 cites W2043873042 @default.
• W2000485959 cites W2045336596 @default.
• W2000485959 cites W2054858499 @default.
• W2000485959 cites W2058363175 @default.
• W2000485959 cites W2058579523 @default.
• W2000485959 cites W2062341863 @default.
• W2000485959 cites W2063765458 @default.
• W2000485959 cites W2064657824 @default.
• W2000485959 cites W2064733652 @default.
• W2000485959 cites W2066761934 @default.
• W2000485959 cites W2067922071 @default.
• W2000485959 cites W2070466728 @default.
• W2000485959 cites W2070844680 @default.
• W2000485959 cites W2071404698 @default.
• W2000485959 cites W2073606426 @default.
• W2000485959 cites W2074102409 @default.
• W2000485959 cites W2075662351 @default.
• W2000485959 cites W2080378599 @default.
• W2000485959 cites W2081526386 @default.
• W2000485959 cites W2085224408 @default.
• W2000485959 cites W2086294034 @default.
• W2000485959 cites W2086957099 @default.
• W2000485959 cites W2086975486 @default.
• W2000485959 cites W2092226069 @default.
• W2000485959 cites W2093361390 @default.
• W2000485959 cites W2094642658 @default.
• W2000485959 cites W2095009224 @default.
• W2000485959 cites W2112969083 @default.
• W2000485959 cites W2114393864 @default.
• W2000485959 cites W2120436453 @default.
• W2000485959 cites W2133524519 @default.
• W2000485959 cites W2134730376 @default.
• W2000485959 cites W2135434315 @default.
• W2000485959 cites W2143981217 @default.
• W2000485959 cites W2151762853 @default.
• W2000485959 cites W2164516500 @default.
• W2000485959 cites W2164912273 @default.
• W2000485959 cites W2337453863 @default.
• W2000485959 cites W2952390900 @default.
• W2000485959 cites W2952953177 @default.
• W2000485959 cites W4298316832 @default.
• W2000485959 doi "https://doi.org/10.1002/chem.200801215" @default.
• W2000485959 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18792023" @default.
• W2000485959 hasPublicationYear "2008" @default.
• W2000485959 type Work @default.
• W2000485959 sameAs 2000485959 @default.
• W2000485959 citedByCount "19" @default.
• W2000485959 countsByYear W20004859592012 @default.
• W2000485959 countsByYear W20004859592013 @default.
• W2000485959 countsByYear W20004859592014 @default.
• W2000485959 countsByYear W20004859592015 @default.
• W2000485959 countsByYear W20004859592016 @default.
• W2000485959 countsByYear W20004859592017 @default.
• W2000485959 countsByYear W20004859592018 @default.
• W2000485959 countsByYear W20004859592019 @default.
• W2000485959 crossrefType "journal-article" @default.
• W2000485959 hasAuthorship W2000485959A5013652065 @default.
• W2000485959 hasAuthorship W2000485959A5027672816 @default.
• W2000485959 hasAuthorship W2000485959A5033107754 @default.
• W2000485959 hasAuthorship W2000485959A5047735009 @default.
• W2000485959 hasAuthorship W2000485959A5047963541 @default.

• next