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• W2000487093 startingPage "1140" @default.
• W2000487093 abstract "Simultaneous tunneling of an electron and nuclei in hydrogen-bonded molecular clusters which support a dipole bound electron is reported. A whole class of systems including hydrogen halide and water dimer anions is predicted to exhibit this effect. A measurable signature of double tunneling is a strong reduction of the tunneling splitting compared to the neutral cluster. Quantum mechanical calculations give for the hydrogen fluoride dimer anion a ground-state tunneling splitting of 114 MHz, while for the first excited vibrational state the tunneling splitting reaches 4.20 GHz." @default.
• W2000487093 created "2016-06-24" @default.
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• W2000487093 date "2000-02-07" @default.
• W2000487093 modified "2023-10-13" @default.
• W2000487093 title "Double Tunneling: An Overlooked Quantum Effect in Anionic Molecular Clusters" @default.
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• W2000487093 doi "https://doi.org/10.1103/physrevlett.84.1140" @default.
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