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- W2000487333 abstract "(Tsi)chlorosilylenoid [Tsi = C(SiMe3)3] reacted with acetaldehyde and benzaldehyde to give 2,4-dioxasilolane and 2,5-dioxasilolane, respectively. The direct addition of an aldehyde to a silaoxirane intermediate is proposed as a plausible mechanism based on a theoretical study. These results show a new synthetic application of the chlorosilylenoid and a new route for the synthesis of silaheterocycles." @default.
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- W2000487333 date "2010-02-18" @default.
- W2000487333 modified "2023-09-25" @default.
- W2000487333 title "New Synthetic Routes for Silaheterocycles: Reactions of a Chlorosilylenoid with Aldehydes" @default.
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- W2000487333 doi "https://doi.org/10.1021/om9008789" @default.
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