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• W2000487620 endingPage "129" @default.
• W2000487620 startingPage "119" @default.
• W2000487620 abstract "A thorough investigation of the reactions of diynes, R(C&tbd1;C)(2)R, and polyynes, R(C&tbd1;C)(n)()R, with titanocene and zirconocene was performed using the metallocene sources Cp(2)M(L)(eta(2)-Me(3)SiC&tbd1;CSiMe(3)) (M = Ti, L = -; M = Zr, L = THF, pyridine). The conversions show an array of different products generated in complexation, coupling, and cleavage reactions. These results include remarkable structures (e.g., five-membered metallacyclocumulenes) and reactions (e.g., C-C single-bond cleavage). In addition, the first C-C single-bond metathesis in homogeneous solution was discovered. The presented findings have been supported by theoretical studies." @default.
• W2000487620 created "2016-06-24" @default.
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• W2000487620 date "2000-01-25" @default.
• W2000487620 modified "2023-10-16" @default.
• W2000487620 title "What Do Titano- and Zirconocenes Do with Diynes and Polyynes?" @default.
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• W2000487620 doi "https://doi.org/10.1021/ar9900109" @default.
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