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• W2000493966 abstract "Norbornene derivatives bearing endo-substituents in the 5- and 6-positions were studied as substrates for ene–yne metathesis cascades. Substrates which contained an internal alkyne and a terminal alkene or alkyne in each sidechain were found to undergo a metathesis cascade leading to pentacyclic bis-dienes and bis-trienes. Attempts to extend the chemistry further to sidechains containing two internal alkynes or two internal alkynes and a terminal alkene were not successful with the first generation Grubbs' catalyst. However, the substrate containing two internal alkynes did react with the second generation Grubbs' catalyst to give a tetra-diene containing product." @default.
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• W2000493966 date "2004-09-01" @default.
• W2000493966 modified "2023-10-16" @default.
• W2000493966 title "Ene–yne metathesis of polyunsaturated norbornene derivatives" @default.
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• W2000493966 doi "https://doi.org/10.1016/j.tet.2004.06.114" @default.
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