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- W2000498787 abstract "Solvation and rotational dynamics were measured using several solvatochromic probes in 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim+][PF6-]) to determine the sensitivity of these dynamics to the choice of probe. In all solutes an unresolved ultrafast component (<5 ps) and highly non-exponential solvation dynamics were observed, consistent with results of prior studies in imidazolium ionic liquids. Solvation times varied by a factor of ∼2 among the probes studied. Rotational correlation functions were generally non-exponential, but in all cases rotation times track solvent viscosity in the same manner as in conventional solvents." @default.
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- W2000498787 date "2004-09-01" @default.
- W2000498787 modified "2023-10-01" @default.
- W2000498787 title "The probe dependence of solvation dynamics and rotation in the ionic liquid 1-butyl-3-methyl-imidazolium hexafluorophosphate" @default.
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- W2000498787 doi "https://doi.org/10.1016/j.cplett.2004.08.018" @default.
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