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- W2000500107 abstract "Thermolysis of enolizable vinyl quinones in polar, aprotic media provides 2H-chromenes. Experimental evidence supports a two-step mechanism in which enolization is followed by a thermal 6pi-electrocyclic reaction of an intermediate quinone methide. Application of this method led to the total synthesis of the reputed structure of an Ageratum juvenile hormone. When enolizable vinyl quinones are the products of Stille coupling, the chromene annulation product is obtained directly. [reaction: see text]" @default.
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- W2000500107 date "2001-10-31" @default.
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- W2000500107 title "Electrocyclic Ring Closure of the Enols of Vinyl Quinones. A <i>2H</i>-Chromene Synthesis" @default.
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- W2000500107 doi "https://doi.org/10.1021/ol0167199" @default.
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