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- W2000500454 abstract "The preparation of diene-modified oligonucleotides as well as their properties and further derivatization are described. Self-complementary oligonucleotides containing a diene moiety in the loop region form stable, hairpin-like secondary structures. These hairpin mimics can be further derivatized via the Diels-Alder reaction. Diene modification in the stem region leads, in contrast, to a marked destabilization of the hairpin structure. No further reduction in stability is observed, however, upon conjugation of the stem-modified derivatives via the Diels-Alder reaction with an N-substituted maleimide dienophile." @default.
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- W2000500454 date "2005-06-29" @default.
- W2000500454 modified "2023-09-23" @default.
- W2000500454 title "Synthesis and Bioconjugation of Diene-Modified Oligonucleotides" @default.
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- W2000500454 doi "https://doi.org/10.1021/bc050025t" @default.
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