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- W2000505642 abstract "Pyrano[3,2-c]benzothiopyrans are synthesized from thiosalicylaldehyde derivatives and unsaturated alcohols in the presence of trimethyl orthoformate and a catalytic amount of p-toluenesulfonic acid with complete trans-stereoselectivity via intramolecular [4+2] cycloaddition of ortho-thioquinonemethides. A more efficient generation and cycloaddition of ortho-thioquinonemethides with Lewis acid is also described." @default.
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- W2000505642 date "2005-07-12" @default.
- W2000505642 modified "2023-09-24" @default.
- W2000505642 title "One-Pot Stereoselective Synthesis of Pyrano[3,2-c]benzothiopyrans: A New Generation and [4 + 2] Cycloaddition of ortho-Thioquinonemethides." @default.
- W2000505642 cites W2949559429 @default.
- W2000505642 doi "https://doi.org/10.1002/chin.200528150" @default.
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