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- W2000506776 abstract "The valence of cerium is deduced from Ce L≥ absorption spectra in various Ce (Rh1-xMx)2Si2 compounds with M = Co, Ru. Its variation versus x in each of the solid solutions is related to the structural and magnetic properties. The cerium remains in a nearly trivalent state in Ce (Rh1-x Rux)2Si2 compounds. This result is related to the formation of the heavy fermion ground-state for x about 0.5. The substitution of rhodium by smaller cobalt atoms in Ce (Rh1-x Cox)2Si2 solid solutions introduces a chemical pressure effect on cerium ions, which undergo a transition into the intermediate state. A quasi-linear decrease of 4f occupancy is observed for the intermediate valence state range of composition." @default.
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- W2000506776 date "1989-02-01" @default.
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- W2000506776 title "Cerium valence and physical properties of Ce(Rh1-xMx)2Si2 solid solutions with M = Co,Ru" @default.
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- W2000506776 doi "https://doi.org/10.1016/0038-1098(89)90221-4" @default.
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