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- W2000508889 abstract "Irradiation at low temperatures (0°C) of alkyl-, aryl- and styryl alkoxychromium(0)carbene complexes in the presence of methyl acrylate produces a mixture of diastereomeric cyclopropanes and C–H insertion derivatives. The ratio cyclopropane/C–H insertion product is independent of the reaction conditions, while the cyclopropane cis : trans ratio strongly depends on the solvent, the selectivity increasing as the polarity of the reaction solvent does. Graphic" @default.
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- W2000508889 date "2001-08-01" @default.
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- W2000508889 title "Low temperature carbene transfer from alkoxychromium(0) (Fischer) carbene complexes" @default.
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- W2000508889 doi "https://doi.org/10.1016/s0040-4039(01)01082-6" @default.
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