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- W2000509624 abstract "A general procedure for the oxidation of catechin derivatives is described, leading to the introduction of a new hydroxyl group at C-6. This procedure has been used for the synthesis of a number of 6-hydroxy flavan-3-ols, including elephantorrhizol, a natural flavan-3-ol exhibiting a fully substituted A ring. The substitution at C-8, albeit of poor influence on the course of this oxidation reaction, has been demonstrated to be preponderant for the further spontaneous oxidation and rearrangement of 6-hydroxy-flavan-3-ols into p-benzoquinones. The whole procedure allows the preparation of 6-alkyl substituted benzoquinones derived from catechin." @default.
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- W2000509624 date "2006-09-04" @default.
- W2000509624 modified "2023-10-06" @default.
- W2000509624 title "Hydroxylation of Ring A of Flavan-3-ols: Influence of the Ring A Substitution Pattern on the Oxidative Rearrangement of 6-Hydroxyflavan-3-ols" @default.
- W2000509624 doi "https://doi.org/10.1055/s-2006-950224" @default.
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