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• W2000512042 abstract "The aluminium(III)-citrate complex (NH(4))(4)[Al(2)(C(6)H(4)O(7))(C(6)H(5)O(7))(2)].4H(2)O was characterized using anion exchange chromatography on-line coupled with the element specific ICP-AES detector. Time-dependent monitoring of individual species in aqueous solution at different temperatures gave information about the species stability and the decomposition pathway. The aluminium-citrate complex (NH(4))(4)[Al(2)(C(6)H(4)O(7))(C(6)H(5)O(7))(2)].4H(2)O disintegrated via an unknown intermediary Al(III)-citrate species from which the thermodynamically stable complex [Al(3)(C(6)H(4)O(7))(3)(OH)(H(2)O)](4-) was formed. The activation energy for the decomposition reaction and the pre-exponential factor were determinated to be E(a)=81.95kJmol(-1) and A=3.62x10(13)s(-1)." @default.
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• W2000512042 date "2009-11-01" @default.
• W2000512042 modified "2023-10-18" @default.
• W2000512042 title "Characterization of an aluminium(III)–citrate species by means of ion chromatography with inductively coupled plasma-atomic emission spectrometry detection" @default.
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• W2000512042 doi "https://doi.org/10.1016/j.chroma.2009.09.025" @default.
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