FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000519166> ?p ?o ?g. }

• W2000519166 abstract "The novel aluminum ethylenediphosphonate fluoride, [HN(CH{sub 2}CH{sub 2}NH{sub 3}){sub 3}][Al{sub 2}(O{sub 3}PCH{sub 2}CH{sub 2}PO{sub 3}){sub 2}F{sub 2}].H{sub 2}O (1) (monoclinic, P2{sub 1}/n, a=12.145(4) A, b=9.265(3) A, c=20.422(6) A, beta=104.952(4){sup o}, Z=3, R{sub 1}=0.092, wR{sub 2}=0.196) has been synthesized by solvothermal methods in the presence of tris(2-aminoethyl)amine and its structure determined using single microcrystal X-ray diffraction data. Compound 1 is a one-dimensional extended chain structure composed of well-separated anionic [Al{sub 2}(O{sub 3}PCH{sub 2}CH{sub 2}PO{sub 3}){sub 2}F{sub 2}]{sup 4-} rods containing helical chains of corner-shared cis-AlO{sub 4}F{sub 2} octahedra at their core. The charge-compensating tris(2-aminoethyl)ammonium cations separate the anionic [Al{sub 2}(O{sub 3}PCH{sub 2}CH{sub 2}PO{sub 3}){sub 2}F{sub 2}]{sup 4-} rods that contain either left- or right-handed helical chains. The incorporation of the organic components into this hybrid material has aided the adoption of one-dimensionality by the compound and defined the pitch of the helical AlO{sub 4}F chain. - Graphical abstract: Helical chains of corner-shared cis-AlO{sub 4}F{sub 2} octahedra form the core of well-separated anionic [Al{sub 2}(O{sub 3}PCH{sub 2}CH{sub 2}PO{sub 3}){sub 2}F{sub 2}]{sup 4-} rods in the novel hybrid aluminum diphosphonate material, (H{sub 4}tren)[Al{sub 2}(O{sub 3}PCH{sub 2}CH{sub 2}PO{sub 3}){sub 2}F{sub 2}].(H{sub 2}O). The incorporation of the organic components into this hybrid material has aidedmore » the adoption of a uni-dimensional structure and a specific structural aspect, the helical pitch, within the resulting material, which indicates the potential of this approach to form particular structural features within hybrid materials.« less" @default.
• W2000519166 created "2016-06-24" @default.
• W2000519166 creator A5033443617 @default.
• W2000519166 creator A5073086619 @default.
• W2000519166 creator A5091708807 @default.
• W2000519166 date "2009-11-01" @default.
• W2000519166 modified "2023-09-25" @default.
• W2000519166 title "Formation of helix-containing rods in a hybrid inorganic–organic material" @default.
• W2000519166 cites W1481355813 @default.
• W2000519166 cites W1963773687 @default.
• W2000519166 cites W1979561325 @default.
• W2000519166 cites W1981312508 @default.
• W2000519166 cites W1982058883 @default.
• W2000519166 cites W1984759401 @default.
• W2000519166 cites W1997924995 @default.
• W2000519166 cites W2007345503 @default.
• W2000519166 cites W2009845070 @default.
• W2000519166 cites W2018510299 @default.
• W2000519166 cites W2020186515 @default.
• W2000519166 cites W2023721071 @default.
• W2000519166 cites W2034263994 @default.
• W2000519166 cites W2042642041 @default.
• W2000519166 cites W2046315625 @default.
• W2000519166 cites W2048432994 @default.
• W2000519166 cites W2052334890 @default.
• W2000519166 cites W2064976770 @default.
• W2000519166 cites W2072436367 @default.
• W2000519166 cites W2086769969 @default.
• W2000519166 cites W2122815782 @default.
• W2000519166 cites W2147388778 @default.
• W2000519166 cites W2158744361 @default.
• W2000519166 cites W2160318699 @default.
• W2000519166 cites W2161662666 @default.
• W2000519166 cites W2891670902 @default.
• W2000519166 cites W4210949282 @default.
• W2000519166 doi "https://doi.org/10.1016/j.jssc.2009.08.021" @default.
• W2000519166 hasPublicationYear "2009" @default.
• W2000519166 type Work @default.
• W2000519166 sameAs 2000519166 @default.
• W2000519166 citedByCount "3" @default.
• W2000519166 countsByYear W20005191662013 @default.
• W2000519166 crossrefType "journal-article" @default.
• W2000519166 hasAuthorship W2000519166A5033443617 @default.
• W2000519166 hasAuthorship W2000519166A5073086619 @default.
• W2000519166 hasAuthorship W2000519166A5091708807 @default.
• W2000519166 hasConcept C115624301 @default.
• W2000519166 hasConcept C120665830 @default.
• W2000519166 hasConcept C121332964 @default.
• W2000519166 hasConcept C178790620 @default.
• W2000519166 hasConcept C185592680 @default.
• W2000519166 hasConcept C198819137 @default.
• W2000519166 hasConcept C207114421 @default.
• W2000519166 hasConcept C32909587 @default.
• W2000519166 hasConcept C50515024 @default.
• W2000519166 hasConcept C61276311 @default.
• W2000519166 hasConcept C71240020 @default.
• W2000519166 hasConcept C8010536 @default.
• W2000519166 hasConcept C91967747 @default.
• W2000519166 hasConceptScore W2000519166C115624301 @default.
• W2000519166 hasConceptScore W2000519166C120665830 @default.
• W2000519166 hasConceptScore W2000519166C121332964 @default.
• W2000519166 hasConceptScore W2000519166C178790620 @default.
• W2000519166 hasConceptScore W2000519166C185592680 @default.
• W2000519166 hasConceptScore W2000519166C198819137 @default.
• W2000519166 hasConceptScore W2000519166C207114421 @default.
• W2000519166 hasConceptScore W2000519166C32909587 @default.
• W2000519166 hasConceptScore W2000519166C50515024 @default.
• W2000519166 hasConceptScore W2000519166C61276311 @default.
• W2000519166 hasConceptScore W2000519166C71240020 @default.
• W2000519166 hasConceptScore W2000519166C8010536 @default.
• W2000519166 hasConceptScore W2000519166C91967747 @default.
• W2000519166 hasLocation W20005191661 @default.
• W2000519166 hasOpenAccess W2000519166 @default.
• W2000519166 hasPrimaryLocation W20005191661 @default.
• W2000519166 hasRelatedWork W1972096880 @default.
• W2000519166 hasRelatedWork W103654859 @default.
• W2000519166 hasRelatedWork W3111950895 @default.
• W2000519166 isParatext "false" @default.
• W2000519166 isRetracted "false" @default.
• W2000519166 magId "2000519166" @default.
• W2000519166 workType "article" @default.