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- W2000521612 abstract "Abstract The rates of oxidation of the 2-, 3- and 4-pyridinecarboxaldehydes by aqueous cobaltic perchlorate in perchloric acid media were found to decrease in the order 4-PA > 3-PA > 2-PA. The reactive species of oxidant was found to be the hydrolyzed cobaltic ion, Co(OH)(H2O)5++, and the reactive species of reductant showed indications of being the hydrated form of the aldehydes. No ionic strength effects were found. The rate law was the same for all three aldehydes, and was found to be Rate = k′2(Co(H2O)6+3)(PA)/(H+. Activation parameters were determined for the reactions of the three aldehydes." @default.
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- W2000521612 date "1974-02-01" @default.
- W2000521612 modified "2023-09-26" @default.
- W2000521612 title "A kinetic study of the oxidation of the 2-, 3- and 4-pyridinecarboxaldehydes by aqueous Co(III) ions" @default.
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- W2000521612 doi "https://doi.org/10.1016/0022-1902(74)80024-2" @default.
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