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• W2000522287 abstract "The growth of Ce on Au(111) was studied with STM and XPS in UHV. Ce islands grew on Au(111) without showing a preference for nucleation at elbows, as reported for some other clusters. XPS data show a shift of up to +0.4 eV for the Au 4f core level with increasing coverage of Ce to 2 ML at room temperature. The Ce 3d core level broadened upon heating, suggesting a strong interaction of Ce atoms with Au atoms. After heating to 470 K, the Au herringbone was distorted into trigonal structures while small Ce clusters with a narrow size distribution decorated the elbows and corners of the trigonal structures. Large islands displaying a moiré pattern grew by alloying Ce atoms with Au surface in a broad size range. The second alloy phase, embedded into the surface as hexagonal islands with corners located on the herringbone stripes, has a strong resistance to oxidation by O2 and NO2. Star-like coplanar structures seen at the intersection of six dislocation stripes are the preferential nucleation sites for the hexagonal islands." @default.
• W2000522287 created "2016-06-24" @default.
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• W2000522287 date "2007-02-09" @default.
• W2000522287 modified "2023-10-18" @default.
• W2000522287 title "STM and XPS Study of Growth of Ce on Au(111)" @default.
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• W2000522287 doi "https://doi.org/10.1021/jp064366v" @default.
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