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• W2000528130 abstract "The aim of this paper is to provide insight into the effect of cation substitution at the B site on the oxygen semi-permeation performances. Particular attention is given here to identify the impact of cation substitution at the B site on oxygen diffusion and oxygen surface-exchange kinetics in the La0.5Ba0.5Fe0.7B0.3O3−δ perovskite membrane series with B = Al, Co, Cu, Mg, Mn, Ni, Sn, Ti and Zn. This study clearly shows that the prediction of the oxygen semi-permeation performances of membrane materials from the nature of cation at the A or B sites in perovskite structure is quite complex. The cation substitution at the B-site has a low impact on the nature of rate-determining step and a significant impact on oxygen semi-permeation performances, contrary to the cation substitution at A-site. Unfortunately, it is not possible to establish a relevant trend about the effect of the nature of cation in the A or B sites in perovskite structure on oxygen diffusion and the oxygen surface-exchange kinetics." @default.
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• W2000528130 date "2015-03-01" @default.
• W2000528130 modified "2023-10-17" @default.
• W2000528130 title "Effect of cation substitution at the B site on the oxygen semi-permeation flux in La 0.5 Ba 0.5 Fe 0.7 B 0.3 O 3−δ dense perovskite membranes with B = Al, Co, Cu, Mg, Mn, Ni, Sn, Ti and Zn (part II)" @default.
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• W2000528130 doi "https://doi.org/10.1016/j.jpowsour.2014.12.012" @default.
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