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- W2000530825 abstract "Hydroboration of 1-trimethylsilyl-1-alkynes with dicyclohexylborane gives 1-trimethylsilylvinylboranes regio- and stereoselectively whose successive treatment with methyllithium, cuprous iodide and alkyl halides affords (Z)-1,2-dialkylvinylsilanes in high yields. Functionalized 1-trimethylsilyl-1-alkynes give analogous results. Successive treatment of the intermediary 1-trimethylsilylvinylboranes with methyllithium and methyl iodide gives 2-trimethylsilyl-2(Z)-alkenes. Allyl halides give 4-trimethylsilyl-1,4(Z)-alkadienes analogously." @default.
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- W2000530825 date "1977-01-01" @default.
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- W2000530825 title "Stereoselective synthesis of vinylsilanes from alkynylsilanes by reductive alkylation via hydroboration, transmetallation and carbodemetallation" @default.
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- W2000530825 doi "https://doi.org/10.1016/0040-4020(77)88034-4" @default.
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