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• W2000532414 abstract "The dependence of the absorption-edge position on ion valence in resonant scattering can be used to analyse the ionic composition of complex oxides. As the diffraction spectra are more sensitive to f^{,prime} than to f^{,primeprime}, the shift in f^{,prime} associated with the valence can be used to refine the cation distribution. Below the absorption edge the shape of f^{,prime} is quite insensitive to other site parameters. High-angle data are important to reach significant variation of the diffraction lines. The feasibility of this method for powder materials was tested using a nanometric powder of magnetite, Fe 3 O 4 . More complex ferrites were then investigated and the results compared with neutron diffraction experiments." @default.
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• W2000532414 date "2003-03-15" @default.
• W2000532414 modified "2023-10-18" @default.
• W2000532414 title "Mixed valences in nanometric ferrites investigated by resonant powder diffraction" @default.
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• W2000532414 doi "https://doi.org/10.1107/s002188980300150x" @default.
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