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- W2000534473 abstract "Abstract The P,P′-dilithium salt of o-phenylenebis(phenylphosphane) reacts with equivalent amounts of subgroup IV metallocene dichlorides, Cp2MCl2 (Cp = η5-C5H5; M = Ti, Zr, Hf), to give the new five-membered chelate complexes Cp2M(1,2-PPhC6H4PPh) (M = Ti, 1; Zr, 2; Hf, 3). Compounds 1–3 can be prepared more conveniently by reaction of o-phenylenebis(phenylphosphane) with equimolar amounts of the dimethylmetallocenes Cp2M(CH3)2 (M = Ti, Zr, Hf). The 31P NMR spectra and the fragmentation of 1–3 in the mass spectra are discussed." @default.
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- W2000534473 date "1988-06-01" @default.
- W2000534473 modified "2023-09-30" @default.
- W2000534473 title "Neue Metallacyclen des Titanocen-, Zirconocen- und Hafnocen-Systems mit P,P′-koordinierten Chelatliganden" @default.
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- W2000534473 doi "https://doi.org/10.1016/0022-328x(88)80136-0" @default.
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