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• W2000534969 abstract "Layered LiAl1/3−xCoxNi1/3Mn1/3O2 (0 ≦ x ≦ 1/3) compounds were studied via the combination of computational and experimental approach. The calculated voltage curve of LiNi1/3Al1/3Mn1/3O2 compound is presented, indicating it is of great potential for a cathode material of lithium-ion batteries. Unfortunately, it was found that the LiNi1/3Al1/3Mn1/3O2 compound without impurity phase could not be synthesized via a sol–gel process. To obtain a layered compound without impurity phase, partial of Al is replaced by Co in LiNi1/3Al1/3Mn1/3O2 compound in this study. Layered LiAl1/3−xCoxNi1/3Mn1/3O2 (0 ≦ x ≦ 1/3) compounds were synthesized via sol–gel reaction at 900 °C under a oxygen stream. Single phase of the LiAl1/3−xCoxNi1/3Mn1/3O2 in 1/6 ≦ x ≦ 1/3 region could be prepared successfully. The discharge capacity and conductivity increased with an increase in the Co-substitution content. The enhancement of the conductivity and phase purity by the introduction of Co content shows profound influence on the performance of the LiAl1/3−xCoxNi1/3Mn1/3O2 compounds." @default.
• W2000534969 created "2016-06-24" @default.
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• W2000534969 date "2006-10-01" @default.
• W2000534969 modified "2023-10-16" @default.
• W2000534969 title "Effect of Co content on performance of LiAl1/3−Co Ni1/3Mn1/3O2 compounds for lithium-ion batteries" @default.
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• W2000534969 doi "https://doi.org/10.1016/j.jpowsour.2006.02.005" @default.
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