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- W2000535588 abstract "Abstract The temperature‐dependent vibrational infrared and Raman spectra of 20% solutions of decylammonium chloride in H 2 O (D 2 O) were studied. According to previous work, phases S I and S II were identified in the low‐temperature range. Molecular and supermolecular structures were derived. The upper shift (Δν = 12 cm −1 ) of the Raman‐active antisymmetric stretching CH 2 mode (d − ) and its narrowness are peculiar and specific signals of a specific structure. It is proposed that the phase transition S I → S II is originated by the onset of a conformational flexibility generally described as twistons or conformational solitons. No evidence was found that the alkyl residues have librational freedom about their axes." @default.
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- W2000535588 date "1994-07-01" @default.
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- W2000535588 title "Structure, intermolecular interactions and molecular mobility in aqueous solutions of decylammonium chloride" @default.
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- W2000535588 doi "https://doi.org/10.1002/jrs.1250250735" @default.
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