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• W2000535622 abstract "The photodissociation of vinyl fluoride following electronic excitation at 157 nm has been studied using the techniques of mass-resolved photofragment time-of-flight spectroscopy. HF elimination has been observed as the main primary dissociation process. This channel has a translational energy distribution peaked at around 20 kcal/mol, indicating that the reaction has a substantial exit barrier. We conclude that HF is mainly produced via four-center elimination. Other primary reactions have also been observed and are tentatively assigned as the CH bond rupture and H2 elimination processes. The mechanisms of the unimolecular reactions of vinyl fluoride are discussed on the basis of ab initio molecular orbital calculations." @default.
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• W2000535622 date "1995-08-01" @default.
• W2000535622 modified "2023-09-24" @default.
• W2000535622 title "Translational distributions of fragments produced in the photodissociation of vinyl fluoride at 157 nm" @default.
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• W2000535622 doi "https://doi.org/10.1016/0009-2614(95)00753-q" @default.
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