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- W2000536197 abstract "Abstract The cyclic thiother ligand tetrahydrothiophene, SC4H8, reacts with transition metal carbonyl clusters HRuCo3(CO)12, HRuRh3(CO)12, H4Ru4(CO)12 and Ru3(CO)12 to give HRuCo3(CO)11(SC4H8) (1), [HRuRh3(CO)9]2[SC4H8]3 (2), H2Ru4(CO)12(SC4H8) (3) and Ru4(CO)13(SC4H8) (4), respectively. The crystal structures of the products fall into three different structural types. In 1 the tetrahydrotriophene displaces a terminal carbonyl ligand at cobalt; whereas in 2 it acts as a bridging four-electron donor to give a dimerized cluster. Both Ru-clusters have butterfly structures with tetrahydrothiophene ligand coordinated between the wingtips." @default.
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- W2000536197 date "1995-01-01" @default.
- W2000536197 modified "2023-10-10" @default.
- W2000536197 title "Tetrahydrothiophene derivatives of metal carbonyl clusters" @default.
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- W2000536197 doi "https://doi.org/10.1016/0022-328x(94)05032-7" @default.
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