Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000541700> ?p ?o ?g. }
Showing items 1 to 85 of
85
with 100 items per page.
- W2000541700 endingPage "4131" @default.
- W2000541700 startingPage "4125" @default.
- W2000541700 abstract "The occurrence of cis or trans configurations in square planar diarylbis(dimethyl sulfoxide)platinum(II) complexes with S-bonded dmso ligands and aryl = 2,3,4,5,6-pentamethylphenyl, 2,4,6-trimethylphenyl, 2,6-dimethylphenyl, 2-, 3-, and 4-methylphenyl, and phenyl has been investigated by multinuclear (1H, 13C, and 195Pt) NMR spectroscopy and crystal structure analysis. Both methods confirm the cis configuration for complexes with the smaller phenyl and methylphenyl (tolyl) ligands and the trans configuration for the compounds with the bulkier ligands, starting from 2,6-dimethylphenyl. Spectroscopic criteria could thus be established to identify configurational isomers. For the 2-tolyl complex an additional kind of isomerism arises from the relative orientation of the two methyl substituents on the same side (syn) or on different sides of the coordination plane (anti). 2D-NMR spectroscopy allowed us to identify the conformers and to study isomerization mechanisms. DFT calculation results agree well with th..." @default.
- W2000541700 created "2016-06-24" @default.
- W2000541700 creator A5020043051 @default.
- W2000541700 creator A5030961872 @default.
- W2000541700 creator A5040385219 @default.
- W2000541700 creator A5043245954 @default.
- W2000541700 creator A5046763720 @default.
- W2000541700 creator A5059647078 @default.
- W2000541700 creator A5061368148 @default.
- W2000541700 creator A5091668895 @default.
- W2000541700 date "2005-07-15" @default.
- W2000541700 modified "2023-09-23" @default.
- W2000541700 title "Multiple Isomerism (<i>cis/trans</i>; <i>s</i><i>yn/</i><i>a</i><i>nti</i>) in [(dmso)<sub>2</sub>Pt(aryl)<sub>2</sub>] Complexes: A Combined Structural, Spectroscopic, and Theoretical Investigation" @default.
- W2000541700 cites W1972981149 @default.
- W2000541700 cites W1986559073 @default.
- W2000541700 cites W1987581647 @default.
- W2000541700 cites W1990905767 @default.
- W2000541700 cites W1999526688 @default.
- W2000541700 cites W2000484306 @default.
- W2000541700 cites W2022273872 @default.
- W2000541700 cites W2037493997 @default.
- W2000541700 cites W2049150887 @default.
- W2000541700 cites W2053844071 @default.
- W2000541700 cites W2079107839 @default.
- W2000541700 cites W2086957099 @default.
- W2000541700 cites W2150345533 @default.
- W2000541700 doi "https://doi.org/10.1021/om050076+" @default.
- W2000541700 hasPublicationYear "2005" @default.
- W2000541700 type Work @default.
- W2000541700 sameAs 2000541700 @default.
- W2000541700 citedByCount "27" @default.
- W2000541700 countsByYear W20005417002012 @default.
- W2000541700 countsByYear W20005417002013 @default.
- W2000541700 countsByYear W20005417002014 @default.
- W2000541700 countsByYear W20005417002015 @default.
- W2000541700 countsByYear W20005417002017 @default.
- W2000541700 countsByYear W20005417002018 @default.
- W2000541700 countsByYear W20005417002021 @default.
- W2000541700 countsByYear W20005417002022 @default.
- W2000541700 crossrefType "journal-article" @default.
- W2000541700 hasAuthorship W2000541700A5020043051 @default.
- W2000541700 hasAuthorship W2000541700A5030961872 @default.
- W2000541700 hasAuthorship W2000541700A5040385219 @default.
- W2000541700 hasAuthorship W2000541700A5043245954 @default.
- W2000541700 hasAuthorship W2000541700A5046763720 @default.
- W2000541700 hasAuthorship W2000541700A5059647078 @default.
- W2000541700 hasAuthorship W2000541700A5061368148 @default.
- W2000541700 hasAuthorship W2000541700A5091668895 @default.
- W2000541700 hasConcept C155647269 @default.
- W2000541700 hasConcept C176788430 @default.
- W2000541700 hasConcept C178790620 @default.
- W2000541700 hasConcept C185592680 @default.
- W2000541700 hasConcept C202235601 @default.
- W2000541700 hasConcept C2780263894 @default.
- W2000541700 hasConcept C2781076698 @default.
- W2000541700 hasConcept C71240020 @default.
- W2000541700 hasConceptScore W2000541700C155647269 @default.
- W2000541700 hasConceptScore W2000541700C176788430 @default.
- W2000541700 hasConceptScore W2000541700C178790620 @default.
- W2000541700 hasConceptScore W2000541700C185592680 @default.
- W2000541700 hasConceptScore W2000541700C202235601 @default.
- W2000541700 hasConceptScore W2000541700C2780263894 @default.
- W2000541700 hasConceptScore W2000541700C2781076698 @default.
- W2000541700 hasConceptScore W2000541700C71240020 @default.
- W2000541700 hasIssue "17" @default.
- W2000541700 hasLocation W20005417001 @default.
- W2000541700 hasOpenAccess W2000541700 @default.
- W2000541700 hasPrimaryLocation W20005417001 @default.
- W2000541700 hasRelatedWork W2021219953 @default.
- W2000541700 hasRelatedWork W2167894278 @default.
- W2000541700 hasRelatedWork W2179929904 @default.
- W2000541700 hasRelatedWork W2324898221 @default.
- W2000541700 hasRelatedWork W2949344611 @default.
- W2000541700 hasRelatedWork W2949408905 @default.
- W2000541700 hasRelatedWork W2950335410 @default.
- W2000541700 hasRelatedWork W2952680289 @default.
- W2000541700 hasRelatedWork W2953390694 @default.
- W2000541700 hasRelatedWork W3011794184 @default.
- W2000541700 hasVolume "24" @default.
- W2000541700 isParatext "false" @default.
- W2000541700 isRetracted "false" @default.
- W2000541700 magId "2000541700" @default.
- W2000541700 workType "article" @default.