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• W2000542145 startingPage "816" @default.
• W2000542145 abstract "The structural connections between the compounds of boron and carbon are extended using the mno rule beyond the borane-carbocation continuum, the lithium boride-polycarbyne analogy, and the magnesium boride (MgB(2))-graphite equivalence to beta-rhombohedral boron and fullerenes. The structural similarity of the pentagonal pyramidal C(6)H(6)(2+) and MgB(4) is established. An interesting electronic structural relationship between the B(84) fragment of the beta-rhombohedral boron and the fulleride anion, C(60)(12-), is derived by replacing the 12 pentagonal pyramidal B(6)(4-) units by isoelectronic C(5)(-) units and removing the central B(12) from the electron-deficient B(84) unit. This relationship is well supported by the experimental realization of C(60)M(12) (M = Li, K) and C(48)N(12)." @default.
• W2000542145 created "2016-06-24" @default.
• W2000542145 creator A5054743387 @default.
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• W2000542145 date "2003-09-13" @default.
• W2000542145 modified "2023-10-16" @default.
• W2000542145 title "Analogies between Boron and Carbon" @default.
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• W2000542145 doi "https://doi.org/10.1021/ar0300266" @default.
• W2000542145 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/14622028" @default.
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