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- W2000545606 abstract "Vinyl acetate (VA) and butyl acrylate (BA) monomers were emulsion copolymerized by using controlled monomer and initiator addition method. Particle size distributions, viscosity average molecular weights (MV), glass-transition temperatures (Tg°) and molar composition of the copolymers were determined. Surface tension components of the copolymer films were calculated from contact angle data of various liquids by using Van Oss—Good methodology. A decrease of average particle size and Tg° was found by the increase of BA content. MV increased up to 40mol% BA, then decreased. Apolar Lifshitz—Van der Waals surface tension component was not affected by the change in BA content; however, electron donor surface tension coefficient (γs−) decreased considerably with the BA increase. The work of adhesion was calculated for cellulosic substrate—latex film interfaces." @default.
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- W2000545606 date "1996-11-01" @default.
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- W2000545606 title "Surface energetics of films of poly(vinyl acetate—butyl acrylate) emulsion copolymers" @default.
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- W2000545606 doi "https://doi.org/10.1016/s0032-3861(96)00385-0" @default.
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