Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000555183> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2000555183 endingPage "1557" @default.
- W2000555183 startingPage "1553" @default.
- W2000555183 abstract "In a demonstration that involves a solvent-free Diels–Alder reaction of (2E,4E)-2,4-hexadien-1-ol and maleic anhydride, one can use relatively small quantities of reactants to illustrate the process of scaling up a solvent-free reaction, including consideration of reactivity of the starting substances, scale of the reaction, and size and shape of the reaction vessel. Upon being mixed, the two solid compounds form a melt and react in the liquid phase to form a solid product. In a 50 mL beaker on a 5.00 mmol scale, the reaction was relatively uneventful. However, an increase to a 10.00 mmol scale in the same size beaker resulted in a vigorous exothermic reaction, which produced dark insoluble syrupy material. When water was added to the reaction mixture, the reaction was faster, with only a modest increase in the reaction temperature and 1,3,3a,4,5,7a-hexahydro-5-methyl-3-oxo-4-isobenzofurancarboxylic acid was obtained as a pure white solid. The demonstration may help students understand the role of solvents in organic reactions, why most reactions are carried out in solvents, as well as potential problems that may be encountered when developing solvent-free reactions." @default.
- W2000555183 created "2016-06-24" @default.
- W2000555183 creator A5023376553 @default.
- W2000555183 creator A5024274367 @default.
- W2000555183 date "2011-08-18" @default.
- W2000555183 modified "2023-10-01" @default.
- W2000555183 title "Demonstration of a Runaway Exothermic Reaction: Diels–Alder Reaction of (2<i>E</i>,4<i>E</i>)-2,4-Hexadien-1-ol and Maleic Anhydride" @default.
- W2000555183 cites W1026967886 @default.
- W2000555183 cites W1965349981 @default.
- W2000555183 cites W1986632012 @default.
- W2000555183 cites W1998745454 @default.
- W2000555183 cites W2025531675 @default.
- W2000555183 cites W2051598964 @default.
- W2000555183 cites W2076892717 @default.
- W2000555183 cites W2079458132 @default.
- W2000555183 cites W2083148479 @default.
- W2000555183 cites W2088881417 @default.
- W2000555183 cites W2110975057 @default.
- W2000555183 cites W2167014804 @default.
- W2000555183 cites W2170185477 @default.
- W2000555183 cites W2330150363 @default.
- W2000555183 cites W2521784411 @default.
- W2000555183 cites W2521859098 @default.
- W2000555183 cites W2952920983 @default.
- W2000555183 cites W4211187039 @default.
- W2000555183 doi "https://doi.org/10.1021/ed100129z" @default.
- W2000555183 hasPublicationYear "2011" @default.
- W2000555183 type Work @default.
- W2000555183 sameAs 2000555183 @default.
- W2000555183 citedByCount "10" @default.
- W2000555183 countsByYear W20005551832013 @default.
- W2000555183 countsByYear W20005551832015 @default.
- W2000555183 countsByYear W20005551832016 @default.
- W2000555183 countsByYear W20005551832020 @default.
- W2000555183 countsByYear W20005551832021 @default.
- W2000555183 countsByYear W20005551832022 @default.
- W2000555183 countsByYear W20005551832023 @default.
- W2000555183 crossrefType "journal-article" @default.
- W2000555183 hasAuthorship W2000555183A5023376553 @default.
- W2000555183 hasAuthorship W2000555183A5024274367 @default.
- W2000555183 hasConcept C142724271 @default.
- W2000555183 hasConcept C15920480 @default.
- W2000555183 hasConcept C161790260 @default.
- W2000555183 hasConcept C175113610 @default.
- W2000555183 hasConcept C177801218 @default.
- W2000555183 hasConcept C178790620 @default.
- W2000555183 hasConcept C185592680 @default.
- W2000555183 hasConcept C188027245 @default.
- W2000555183 hasConcept C204787440 @default.
- W2000555183 hasConcept C2776910235 @default.
- W2000555183 hasConcept C2777666793 @default.
- W2000555183 hasConcept C2779940776 @default.
- W2000555183 hasConcept C2780471494 @default.
- W2000555183 hasConcept C2781206178 @default.
- W2000555183 hasConcept C45119746 @default.
- W2000555183 hasConcept C521977710 @default.
- W2000555183 hasConcept C71924100 @default.
- W2000555183 hasConceptScore W2000555183C142724271 @default.
- W2000555183 hasConceptScore W2000555183C15920480 @default.
- W2000555183 hasConceptScore W2000555183C161790260 @default.
- W2000555183 hasConceptScore W2000555183C175113610 @default.
- W2000555183 hasConceptScore W2000555183C177801218 @default.
- W2000555183 hasConceptScore W2000555183C178790620 @default.
- W2000555183 hasConceptScore W2000555183C185592680 @default.
- W2000555183 hasConceptScore W2000555183C188027245 @default.
- W2000555183 hasConceptScore W2000555183C204787440 @default.
- W2000555183 hasConceptScore W2000555183C2776910235 @default.
- W2000555183 hasConceptScore W2000555183C2777666793 @default.
- W2000555183 hasConceptScore W2000555183C2779940776 @default.
- W2000555183 hasConceptScore W2000555183C2780471494 @default.
- W2000555183 hasConceptScore W2000555183C2781206178 @default.
- W2000555183 hasConceptScore W2000555183C45119746 @default.
- W2000555183 hasConceptScore W2000555183C521977710 @default.
- W2000555183 hasConceptScore W2000555183C71924100 @default.
- W2000555183 hasIssue "11" @default.
- W2000555183 hasLocation W20005551831 @default.
- W2000555183 hasOpenAccess W2000555183 @default.
- W2000555183 hasPrimaryLocation W20005551831 @default.
- W2000555183 hasRelatedWork W1985350140 @default.
- W2000555183 hasRelatedWork W1990537886 @default.
- W2000555183 hasRelatedWork W2000555183 @default.
- W2000555183 hasRelatedWork W2017274378 @default.
- W2000555183 hasRelatedWork W2036685919 @default.
- W2000555183 hasRelatedWork W2051169842 @default.
- W2000555183 hasRelatedWork W2055631046 @default.
- W2000555183 hasRelatedWork W2147399189 @default.
- W2000555183 hasRelatedWork W2314381925 @default.
- W2000555183 hasRelatedWork W2952684408 @default.
- W2000555183 hasVolume "88" @default.
- W2000555183 isParatext "false" @default.
- W2000555183 isRetracted "false" @default.
- W2000555183 magId "2000555183" @default.
- W2000555183 workType "article" @default.