FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000557582> ?p ?o ?g. }

• W2000557582 endingPage "63" @default.
• W2000557582 startingPage "51" @default.
• W2000557582 abstract "Abstract The elusive, multiple fully extended (2.0 5 ‐helix) peptide conformation was searched with a series of C α,α ‐diethylglycine homo‐oligomers (n = 1 to 5) functionalized by an electron transfer (ET) donor···acceptor (D···A) pair in acetonitrile and chloroform solutions. In the former solvent, all peptides investigated were shown to populate the 3 10 ‐helix conformation, whereas in chloroform the two shortest members of the series (n = 1 and n = 2) adopt predominantly the 2.0 5 ‐helix. Interestingly, for the longest components (n = 3 to n = 5) in this latter solvent, an equilibrium between the 2.0 5 ‐ and 3 10 ‐helices takes place, the latter conformation becoming progressively more populated as the peptide main‐chain length increases. Time‐resolved fluorescence (TRF) experiments and molecular mechanics (MM) calculations were used in a combined approach to analyze the ET efficiencies and to associate a specific conformer (from MM) to an experimentally determined ET rate constant (from TRF). Therefore, because of the high sensitivity of the ET process to the D···A distance, ET can be used as a kinetic spectroscopic ruler, allowing for the characterization of the transition from a pure 3 10 ‐helix conformation to a 2.0 5 ‐/3 10 ‐helix equilibrium for the longest Deg homo‐peptides of this series upon changing the solvent from acetonitrile to chloroform. To our knowledge, this is the first time that the electronic coupling factor β for ET across a peptide chain in the 2.0 5 ‐helix conformation is provided. © 2012 Wiley Periodicals, Inc. Biopolymers (Pept Sci) 100: 51–63, 2013." @default.
• W2000557582 created "2016-06-24" @default.
• W2000557582 creator A5009662722 @default.
• W2000557582 creator A5026290894 @default.
• W2000557582 creator A5040500402 @default.
• W2000557582 creator A5041037967 @default.
• W2000557582 creator A5049224701 @default.
• W2000557582 creator A5061528156 @default.
• W2000557582 creator A5064217287 @default.
• W2000557582 creator A5065741079 @default.
• W2000557582 creator A5084260559 @default.
• W2000557582 date "2013-01-01" @default.
• W2000557582 modified "2023-10-16" @default.
• W2000557582 title "Looking for the peptide 2.0₅‐helix: A solvent‐ and main‐chain length‐dependent conformational switch probed by electron transfer across c^α,α‐diethylglycine homo‐oligomers" @default.
• W2000557582 cites W1972107295 @default.
• W2000557582 cites W1972782132 @default.
• W2000557582 cites W1973519346 @default.
• W2000557582 cites W1980071134 @default.
• W2000557582 cites W1980749564 @default.
• W2000557582 cites W1985347140 @default.
• W2000557582 cites W1991673513 @default.
• W2000557582 cites W1991845708 @default.
• W2000557582 cites W1994541938 @default.
• W2000557582 cites W1996295842 @default.
• W2000557582 cites W1997138312 @default.
• W2000557582 cites W2004916798 @default.
• W2000557582 cites W2005471138 @default.
• W2000557582 cites W2005929034 @default.
• W2000557582 cites W2013467098 @default.
• W2000557582 cites W2018950408 @default.
• W2000557582 cites W2025224346 @default.
• W2000557582 cites W2026232127 @default.
• W2000557582 cites W2027799114 @default.
• W2000557582 cites W2030019569 @default.
• W2000557582 cites W2031588870 @default.
• W2000557582 cites W2031904472 @default.
• W2000557582 cites W2032757910 @default.
• W2000557582 cites W2035676316 @default.
• W2000557582 cites W2035956756 @default.
• W2000557582 cites W2038631191 @default.
• W2000557582 cites W2042587535 @default.
• W2000557582 cites W2044990980 @default.
• W2000557582 cites W2046159209 @default.
• W2000557582 cites W2047000897 @default.
• W2000557582 cites W2055660544 @default.
• W2000557582 cites W2061663059 @default.
• W2000557582 cites W2064335622 @default.
• W2000557582 cites W2070279973 @default.
• W2000557582 cites W2071570158 @default.
• W2000557582 cites W2072616847 @default.
• W2000557582 cites W2081778026 @default.
• W2000557582 cites W2082405565 @default.
• W2000557582 cites W2086995578 @default.
• W2000557582 cites W2089680086 @default.
• W2000557582 cites W2093083576 @default.
• W2000557582 cites W2098829554 @default.
• W2000557582 cites W2101871052 @default.
• W2000557582 cites W2105348198 @default.
• W2000557582 cites W2120563372 @default.
• W2000557582 cites W2158161135 @default.
• W2000557582 cites W2491458126 @default.
• W2000557582 cites W2949468084 @default.
• W2000557582 cites W2949816403 @default.
• W2000557582 cites W2952109782 @default.
• W2000557582 doi "https://doi.org/10.1002/bip.22190" @default.
• W2000557582 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23335167" @default.
• W2000557582 hasPublicationYear "2013" @default.
• W2000557582 type Work @default.
• W2000557582 sameAs 2000557582 @default.
• W2000557582 citedByCount "13" @default.
• W2000557582 countsByYear W20005575822014 @default.
• W2000557582 countsByYear W20005575822015 @default.
• W2000557582 countsByYear W20005575822016 @default.
• W2000557582 countsByYear W20005575822018 @default.
• W2000557582 countsByYear W20005575822021 @default.
• W2000557582 countsByYear W20005575822023 @default.
• W2000557582 crossrefType "journal-article" @default.
• W2000557582 hasAuthorship W2000557582A5009662722 @default.
• W2000557582 hasAuthorship W2000557582A5026290894 @default.
• W2000557582 hasAuthorship W2000557582A5040500402 @default.
• W2000557582 hasAuthorship W2000557582A5041037967 @default.
• W2000557582 hasAuthorship W2000557582A5049224701 @default.
• W2000557582 hasAuthorship W2000557582A5061528156 @default.
• W2000557582 hasAuthorship W2000557582A5064217287 @default.
• W2000557582 hasAuthorship W2000557582A5065741079 @default.
• W2000557582 hasAuthorship W2000557582A5084260559 @default.
• W2000557582 hasConcept C178790620 @default.
• W2000557582 hasConcept C185592680 @default.
• W2000557582 hasConcept C18705241 @default.
• W2000557582 hasConcept C18903297 @default.
• W2000557582 hasConcept C2777463227 @default.
• W2000557582 hasConcept C2778530040 @default.
• W2000557582 hasConcept C2779281246 @default.
• W2000557582 hasConcept C2779965526 @default.
• W2000557582 hasConcept C2780471494 @default.
• W2000557582 hasConcept C2781144210 @default.
• W2000557582 hasConcept C32909587 @default.
• W2000557582 hasConcept C55493867 @default.

• next