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- W2000558657 abstract "Abstract The empirical form of the rate law for the oxidation of ascorbic acid (AA) by Np(VI) in aqueous perchloric acid media is -d[Np(VI)]dt = k[Np(VI)] [AA]. The value of k at 25°C and in 1.0 M HClO4 = (1.23±0.02) × 105 M−1 sec−1 No hydrogen ion dependent path of kinetic significance exists over the range 0.05 ΔH ∗ and ΔS ∗ were 7.02±0.07 kcal/mole and −11.7 ± 0.3 e.u., respective The results of this study are compared with those obtained using other metal ion oxidants." @default.
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- W2000558657 date "1978-01-01" @default.
- W2000558657 modified "2023-09-26" @default.
- W2000558657 title "A kinetic study of the oxidation of ascorbic acid by Np(VI) in aqueous acidic perchlorate media" @default.
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- W2000558657 doi "https://doi.org/10.1016/0022-1902(78)80253-x" @default.
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