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- W2000558835 abstract "In recent years, inconsistent space groups of monoclinic B 1 a 1 and orthorhombic B 2 cb have been reported for the room-temperature ferroelectric phases of both Bi 4 Ti 3 O 12 and lanthanide-substituted Bi 4 Ti 3 O 12 . In this article, the electron diffraction technique is employed to unambiguously clarify the crystal symmetries of ferroelectric Bi 4 Ti 3 O 12 and Bi 3.15 Nd 0.85 Ti 3 O 12 single crystals at room temperature. All the reflections observed from the two crystals match well with those derived from B 1 a 1, but the observed reflections 010, 030, {overline 2}10 and {overline 2}30 should be forbidden in the case of B 2 cb . This fact indicates that both the ferroelectrics are of the space group B 1 a 1 rather than B 2 cb , which is confirmed by convergent-beam electron diffraction observations. On the basis of the monoclinic space group B 1 a 1, the lattice parameters of both the ferroelectrics were calculated by the Rietveld refinement of powder X-ray diffraction data." @default.
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- W2000558835 date "2013-05-15" @default.
- W2000558835 modified "2023-10-18" @default.
- W2000558835 title "Determination of crystal symmetry for Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub>-based ferroelectrics by using electron diffraction" @default.
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- W2000558835 doi "https://doi.org/10.1107/s0021889813009126" @default.
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