Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000559585> ?p ?o ?g. }
Showing items 1 to 93 of
93
with 100 items per page.
- W2000559585 endingPage "1529" @default.
- W2000559585 startingPage "1524" @default.
- W2000559585 abstract "In the present paper the synthesis of stable Cu-containing pillared clays catalysts (Cu-PILCs) is described. These catalysts were prepared by the solid-state reaction of Al-pillared clay with copper nitrate. The resultant materials were then treated with an oxalic acid solution in order to improve the dispersion of metal species on the alumina pillars. Characterization studies were performed by use of X-ray diffraction, nitrogen adsorption at 77 K, chemical analysis, temperature-programmed reduction (H2-TPR) and transmission electron microscopy (TEM). The texture of the copper catalysts showed a high specific surface area and microporosity (197 m2 g−1 and 0.081 cm3 g−1 respectively for the catalyst Cu5.6Al-PILC), with high loading of copper (up to 4.72Cu wt%). TPRprofiles of catalysts show the presence of isolated copper species with high interaction with the alumina pillars. The properties of copper-based catalysts have been studied in the wet hydrogen peroxide oxidation of an aqueous solution of tyrosol, a molecule which constitutes more than half of the light fraction of the olive mill wastewater. The reaction was conducted in batch and flow reactors. Performance of catalysts remained quite excellent; total removal of tyrosol with high TOC abatement (around 65%) was obtained after 2 h reaction. Furthermore, the Cu5.6Al-PILC(t) catalyst showed very high stability and performance in the flow reactor: 90% of tyrosol conversion and 78% of TOC removal are obtained in 192 h on stream, without the detection of any change in the activity." @default.
- W2000559585 created "2016-06-24" @default.
- W2000559585 creator A5002518623 @default.
- W2000559585 creator A5005035714 @default.
- W2000559585 creator A5045277886 @default.
- W2000559585 creator A5051874522 @default.
- W2000559585 date "2012-12-01" @default.
- W2000559585 modified "2023-10-14" @default.
- W2000559585 title "Synthesis of stable Cu-supported pillared clays for wet tyrosol oxidation with H2O2" @default.
- W2000559585 cites W1275118280 @default.
- W2000559585 cites W1604278632 @default.
- W2000559585 cites W1763613974 @default.
- W2000559585 cites W1965422607 @default.
- W2000559585 cites W1968037607 @default.
- W2000559585 cites W1970112556 @default.
- W2000559585 cites W1973187292 @default.
- W2000559585 cites W1975921755 @default.
- W2000559585 cites W1978749319 @default.
- W2000559585 cites W1979260051 @default.
- W2000559585 cites W1980251272 @default.
- W2000559585 cites W1985723708 @default.
- W2000559585 cites W2000334802 @default.
- W2000559585 cites W2002697585 @default.
- W2000559585 cites W2010303468 @default.
- W2000559585 cites W2010530773 @default.
- W2000559585 cites W2021678710 @default.
- W2000559585 cites W2042198744 @default.
- W2000559585 cites W2042653583 @default.
- W2000559585 cites W2053290041 @default.
- W2000559585 cites W2055597156 @default.
- W2000559585 cites W2058115426 @default.
- W2000559585 cites W2065765182 @default.
- W2000559585 cites W2073948920 @default.
- W2000559585 cites W2086438667 @default.
- W2000559585 cites W2094555696 @default.
- W2000559585 cites W2153634470 @default.
- W2000559585 cites W2160908295 @default.
- W2000559585 doi "https://doi.org/10.1016/j.jpcs.2012.04.010" @default.
- W2000559585 hasPublicationYear "2012" @default.
- W2000559585 type Work @default.
- W2000559585 sameAs 2000559585 @default.
- W2000559585 citedByCount "3" @default.
- W2000559585 countsByYear W20005595852014 @default.
- W2000559585 countsByYear W20005595852015 @default.
- W2000559585 countsByYear W20005595852017 @default.
- W2000559585 crossrefType "journal-article" @default.
- W2000559585 hasAuthorship W2000559585A5002518623 @default.
- W2000559585 hasAuthorship W2000559585A5005035714 @default.
- W2000559585 hasAuthorship W2000559585A5045277886 @default.
- W2000559585 hasAuthorship W2000559585A5051874522 @default.
- W2000559585 hasConcept C13965031 @default.
- W2000559585 hasConcept C161790260 @default.
- W2000559585 hasConcept C178790620 @default.
- W2000559585 hasConcept C179104552 @default.
- W2000559585 hasConcept C184651966 @default.
- W2000559585 hasConcept C185592680 @default.
- W2000559585 hasConcept C2777728882 @default.
- W2000559585 hasConcept C2781346138 @default.
- W2000559585 hasConcept C2781397249 @default.
- W2000559585 hasConcept C533411734 @default.
- W2000559585 hasConcept C544778455 @default.
- W2000559585 hasConceptScore W2000559585C13965031 @default.
- W2000559585 hasConceptScore W2000559585C161790260 @default.
- W2000559585 hasConceptScore W2000559585C178790620 @default.
- W2000559585 hasConceptScore W2000559585C179104552 @default.
- W2000559585 hasConceptScore W2000559585C184651966 @default.
- W2000559585 hasConceptScore W2000559585C185592680 @default.
- W2000559585 hasConceptScore W2000559585C2777728882 @default.
- W2000559585 hasConceptScore W2000559585C2781346138 @default.
- W2000559585 hasConceptScore W2000559585C2781397249 @default.
- W2000559585 hasConceptScore W2000559585C533411734 @default.
- W2000559585 hasConceptScore W2000559585C544778455 @default.
- W2000559585 hasIssue "12" @default.
- W2000559585 hasLocation W20005595851 @default.
- W2000559585 hasOpenAccess W2000559585 @default.
- W2000559585 hasPrimaryLocation W20005595851 @default.
- W2000559585 hasRelatedWork W1979424755 @default.
- W2000559585 hasRelatedWork W1991270171 @default.
- W2000559585 hasRelatedWork W2003996558 @default.
- W2000559585 hasRelatedWork W2007705132 @default.
- W2000559585 hasRelatedWork W2055285704 @default.
- W2000559585 hasRelatedWork W2082205247 @default.
- W2000559585 hasRelatedWork W2094349411 @default.
- W2000559585 hasRelatedWork W2340932621 @default.
- W2000559585 hasRelatedWork W2421674257 @default.
- W2000559585 hasRelatedWork W2952785262 @default.
- W2000559585 hasVolume "73" @default.
- W2000559585 isParatext "false" @default.
- W2000559585 isRetracted "false" @default.
- W2000559585 magId "2000559585" @default.
- W2000559585 workType "article" @default.