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• W2000559961 abstract "The signs of all 13C19F and 1H–19F coupling constants in fluorobenzene, some substituted derivatives, and in 2-fluoropyridine have been related using single-frequency 13C{1H} double resonance techniques. All 13C19F couplings in these compounds are shown to be positive. Direct experimental proof is given for a positive sign for the small five-bond 1H19F coupling constant (=0.2—0.3 Hz) in fluorobenzene. The positive sign for 4J(C-4, F) in fluorobenzene is in accord with a positive π-electron contribution to this coupling." @default.
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• W2000559961 date "1979-04-01" @default.
• W2000559961 modified "2023-10-16" @default.
• W2000559961 title "A13C{1H} double resonance study of the signs of1H19F and13C19F spin coupling constants in fluorobenzenes and 2-fluoropyridine" @default.
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• W2000559961 doi "https://doi.org/10.1002/mrc.1270120415" @default.
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