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- W2000560966 abstract "The Raman spectra of melt-quenched $mathrm{Ge}{({mathrm{Se}}_{x}{mathrm{Se}}_{1ensuremath{-}x})}_{2}$ glasses are discussed for $x=0.25$. The spectra show well-defined mixed-anion ${A}_{1}$-like breathing modes of $mathrm{Ge}{mathrm{S}}_{frac{n}{2}}{mathrm{Se}}_{frac{(4ensuremath{-}h)}{2}}$ tetrahedra whose frequencies scale rougly with the corresponding modes of $mathrm{Ge}{mathrm{Cl}}_{n}{mathrm{Br}}_{4ensuremath{-}n}$ molecules. Quantititative examination of the scaling factors shows that the scaling in the glass is strongly modified by ${A}_{1}ensuremath{-}{F}_{2}$ mode-mode interactions produced by the loss of ${A}_{1}$ symmetry and greatly enhanced intertetrahedral interactions." @default.
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- W2000560966 date "1982-09-15" @default.
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- W2000560966 title "Local modes in tetrahedralGe(SxSe1−x)2glasses" @default.
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- W2000560966 doi "https://doi.org/10.1103/physrevb.26.3499" @default.
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