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- W2000561243 abstract "The structure of the ZnCl2CdCl2Li,K/Cl and AlCl3MgCl2Li,K/Cl melts has been studied by Raman spectroscopy over a wide complexing metal concentration range. The spectroscopic criteria of heteronuclear-complex formation have been established: when the instability constants (or Gibbs energies) of the individual complex ions ZnCl42− and CdCl42− are close to each other, the v1 (A1) frequency disappears from the Raman spectra of these complexes, and a new ZnClCd bond vibration line appears. When the stability characteristics of the individual complex ions AlCl4− and MgCl42− are different but high, a decrease in the vibration frequency and intensity of the MgCl42− complex due to a weakening of the Mg2+Cl− bond is observed besides the appearance of a new AlClMg bond vibration frequency in the Raman spectrum." @default.
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- W2000561243 date "1999-12-01" @default.
- W2000561243 modified "2023-09-26" @default.
- W2000561243 title "Raman spectroscopy of the heteronuclear complexes in the ZnCl2CdCl2Li,K/Cl and AlCl3MgCl2Li,K/Cl melts" @default.
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- W2000561243 doi "https://doi.org/10.1016/s0167-7322(99)00080-x" @default.
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