FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000563355> ?p ?o ?g. }

• W2000563355 endingPage "403" @default.
• W2000563355 startingPage "395" @default.
• W2000563355 abstract "Seven new coordination polymers {[Cu3(tib)4](NO3)6·4.94H2O}n (1), {[Cu2(tib)2(SO4)2]·2EtOH·2H2O}n (2), [Cu(tib)Cl2]n (3), {[Cd(tib)2](NO3)2·4H2O}n (4), {[Cd(tib)(H2O)2(SO4)]·EtOH·H2O}n (5) {[Co(tib)(H2O)2(SO4)]·EtOH·H2O}n (6), and {[Ni(tib)(H2O)2(SO4)]·EtOH·H2O}n (7) (EtOH = ethanol) were prepared by reactions of flexible tripodal ligand 1,3,5-tris(imidazol-1-ylmethyl)benzene (tib) with the corresponding metal salts. Their structures were determined by X-ray crystallography. The different structures of 1−3 as well as 4 and 5 indicate that the counteranions play an important role in the construction of coordination polymers. The distinct structures of Cu(II) and Cd(II) complexes with the same counteranion demonstrate that the metal centers with different coordination geometry have a significant influence on the structures. The same 1D chain structure of 5−7 indicated that the metal centers with the same octahedral coordination geometry do not affect the structure of the complexes. On the other hand, ligand tib acts as a three-connecting linker to connect three M(II) centers with different conformations. In 1, two different conformations (cis, trans, trans-, and trans-) of tib coexist. In 2−4, tib adopts the cis, trans, trans-conformation, while in the case of 5−7, tib has the cis, cis, cis-conformation. The results attest that the flexible tripodal ligand tib can adopt different conformations to form complexes with varied structures. Furthermore, the reversible anion exchange properties of 1 and 4 were studied." @default.
• W2000563355 created "2016-06-24" @default.
• W2000563355 creator A5006047811 @default.
• W2000563355 creator A5007599353 @default.
• W2000563355 creator A5033661039 @default.
• W2000563355 creator A5036287984 @default.
• W2000563355 creator A5038970546 @default.
• W2000563355 creator A5042333346 @default.
• W2000563355 creator A5059511373 @default.
• W2000563355 creator A5077266193 @default.
• W2000563355 creator A5079430348 @default.
• W2000563355 date "2008-11-19" @default.
• W2000563355 modified "2023-10-10" @default.
• W2000563355 title "Coordination Polymers with Varied Metal Centers and Flexible Tripodal Ligand 1,3,5-Tris(imidazol-1-ylmethyl)benzene: Synthesis, Structure, and Reversible Anion Exchange Property" @default.
• W2000563355 cites W1544546998 @default.
• W2000563355 cites W1756260249 @default.
• W2000563355 cites W1832964000 @default.
• W2000563355 cites W1910574701 @default.
• W2000563355 cites W1965428631 @default.
• W2000563355 cites W1967892157 @default.
• W2000563355 cites W1969877847 @default.
• W2000563355 cites W1970280331 @default.
• W2000563355 cites W1993275801 @default.
• W2000563355 cites W1999937609 @default.
• W2000563355 cites W2007203236 @default.
• W2000563355 cites W2022123160 @default.
• W2000563355 cites W2028805274 @default.
• W2000563355 cites W2031876508 @default.
• W2000563355 cites W2036670935 @default.
• W2000563355 cites W2044428678 @default.
• W2000563355 cites W2055975340 @default.
• W2000563355 cites W2059599439 @default.
• W2000563355 cites W2059782200 @default.
• W2000563355 cites W2066615417 @default.
• W2000563355 cites W2067251026 @default.
• W2000563355 cites W2071138150 @default.
• W2000563355 cites W2080956049 @default.
• W2000563355 cites W2086149075 @default.
• W2000563355 cites W2089848237 @default.
• W2000563355 cites W2092010193 @default.
• W2000563355 cites W2093655659 @default.
• W2000563355 cites W2101853831 @default.
• W2000563355 cites W2114915191 @default.
• W2000563355 cites W2115311487 @default.
• W2000563355 cites W2116030281 @default.
• W2000563355 cites W2126103196 @default.
• W2000563355 cites W2128067355 @default.
• W2000563355 cites W2134961549 @default.
• W2000563355 cites W2144986218 @default.
• W2000563355 cites W2156165678 @default.
• W2000563355 cites W2162269257 @default.
• W2000563355 cites W2162839356 @default.
• W2000563355 cites W2325233941 @default.
• W2000563355 cites W4255610297 @default.
• W2000563355 cites W4379184131 @default.
• W2000563355 doi "https://doi.org/10.1021/cg800600g" @default.
• W2000563355 hasPublicationYear "2008" @default.
• W2000563355 type Work @default.
• W2000563355 sameAs 2000563355 @default.
• W2000563355 citedByCount "66" @default.
• W2000563355 countsByYear W20005633552012 @default.
• W2000563355 countsByYear W20005633552013 @default.
• W2000563355 countsByYear W20005633552014 @default.
• W2000563355 countsByYear W20005633552015 @default.
• W2000563355 countsByYear W20005633552016 @default.
• W2000563355 countsByYear W20005633552017 @default.
• W2000563355 countsByYear W20005633552018 @default.
• W2000563355 countsByYear W20005633552019 @default.
• W2000563355 countsByYear W20005633552020 @default.
• W2000563355 countsByYear W20005633552021 @default.
• W2000563355 countsByYear W20005633552022 @default.
• W2000563355 crossrefType "journal-article" @default.
• W2000563355 hasAuthorship W2000563355A5006047811 @default.
• W2000563355 hasAuthorship W2000563355A5007599353 @default.
• W2000563355 hasAuthorship W2000563355A5033661039 @default.
• W2000563355 hasAuthorship W2000563355A5036287984 @default.
• W2000563355 hasAuthorship W2000563355A5038970546 @default.
• W2000563355 hasAuthorship W2000563355A5042333346 @default.
• W2000563355 hasAuthorship W2000563355A5059511373 @default.
• W2000563355 hasAuthorship W2000563355A5077266193 @default.
• W2000563355 hasAuthorship W2000563355A5079430348 @default.
• W2000563355 hasConcept C112887158 @default.
• W2000563355 hasConcept C115624301 @default.
• W2000563355 hasConcept C116569031 @default.
• W2000563355 hasConcept C170493617 @default.
• W2000563355 hasConcept C178790620 @default.
• W2000563355 hasConcept C185592680 @default.
• W2000563355 hasConcept C194196696 @default.
• W2000563355 hasConcept C198819137 @default.
• W2000563355 hasConcept C2777691172 @default.
• W2000563355 hasConcept C2779868791 @default.
• W2000563355 hasConcept C2781432337 @default.
• W2000563355 hasConcept C32909587 @default.
• W2000563355 hasConcept C39297587 @default.
• W2000563355 hasConcept C544153396 @default.
• W2000563355 hasConcept C55493867 @default.
• W2000563355 hasConcept C71240020 @default.
• W2000563355 hasConcept C8010536 @default.

• next