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- W2000565145 abstract "The optically active poly[{(R)-3,7-dimethyloctyl-(S)-3-methylpentylsilane}-co-{decylisobutyl- silane}](PS-1) underwent a thermodriven helix−helix transition at 13 °C in isooctane. The casting of polymer solution from the pre- and post-transition temperatures led to P (right-handed) or M (left-handed) helical films, which gave positive and negative Cotton circular dichroism (CD) signals, respectively. This result suggests that the helical sense of PS-1 below and above transition temperature in the homogeneous solution was memorized in the cast films. Furthermore, the CD spectra of P- and M-helical films were mirror images to each other at 319 nm, indicating the 73 helical pitch of the polymers with opposite helical sense." @default.
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- W2000565145 date "2004-09-08" @default.
- W2000565145 modified "2023-10-11" @default.
- W2000565145 title "Helical Shape Memory of Screw-Sense Switchable Polysilanes in Cast Films" @default.
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- W2000565145 doi "https://doi.org/10.1021/cm0495616" @default.
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