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• W2000566305 abstract "Abstract Distribution equilibrium data have been obtained for the systems LnCl3HClH2O1M D2EHPA in n-heptane (Ln: Sm, Eu and Gd). The equilibrium curves were described using equilibrium acid concentration as a parameter. It was shown that the distribution ratios of the lanthanides were proportional to CHX2.2 or CHX2.5 (CHX represents the concentration of the extractant) according to the estimated value for the ratio of the extractant to the metal in the extracted species. Equilibrium data for the systems involving SmCl3EuCl3 and EuCl3GdCl3 have been obtained. In these systems the concentrations of individual lanthanides in the organic phase deviated from the expected values based on the assumption that the distribution ratio of each lanthanide was not varied by adding the other lanthanides. The concentrations of the heavier lanthanides, Eu in SmEu system and Gd in EuGd system, in the organic phase were higher than the expected values, and those of the lighter lanthanides were lower than the expected values. These behaviors of the lanthanides were explained in terms of the change of the concentrations of the hydrogen ion and the extractant." @default.
• W2000566305 created "2016-06-24" @default.
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• W2000566305 date "1975-05-01" @default.
• W2000566305 modified "2023-09-27" @default.
• W2000566305 title "Distribution equilibria of SmCl3EuCl3HCl and EuCl3GdCl3HCl systems with 1M di(2-ethylhexyl) phosphoric acid in n-heptane" @default.
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• W2000566305 doi "https://doi.org/10.1016/0022-1902(75)80477-5" @default.
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