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- W2000573689 abstract "The complexation of dysprosium(III), as the model cation for calcium(II), with a series of (hydroxy)carboxylates in aqueous medium, has been studied by 17O NMR spectroscopy. Acetate, 3-hydroxybutyrate, glycolate, lactate, malonate, malate and citrate show fast ligand exchange on the 17O NMR time scale at 73°. The Dy(III)-induced 17O shifts of both the ligand and the water, which are mainly due to contact interaction, provide valuable information on the complexation sites of the ligands as well as on the number of coordinated waters in the complexes. The results point to a rather constant 17O contact shift upon the formation of Dy(III)-O bonds. On the other hand, oxydiacetate (ODA), (carboxymethoxy)succinate (CMOS) and nitrilotriacetate (NTA) show slow ligand exchange on the 17O NMR time scale at 73°. In these cases the Dy(III)-induced shift of the 17O water resonance provides information on the stoichiometry of the complexes, i.e. the number of coordinated waters and the number of ligands." @default.
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- W2000573689 date "2010-09-02" @default.
- W2000573689 modified "2023-09-25" @default.
- W2000573689 title "A study of lanthanide(III) (hydroxy)carboxylate complexes in aqueous medium using lanthanide induced oxygen-17 NMR shifts" @default.
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- W2000573689 doi "https://doi.org/10.1002/recl.19800991208" @default.
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