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- W2000574610 abstract "Abstract Four new coordination polymers, [M(Hiso)(H2O)3]n (M = Co (1); M = Ni (2)) and {[M2(Hiso)2(bipy)2(H2O)4] · 2(bipy)}n (M = Co (3); M = Ni (4)) (H2iso = isoorotic acid, bipy = 4,4′-bipyridine), were synthesized by hydrothermal reactions and characterized by single-crystal X-ray diffraction. The four complexes all comprise 1D chains that are further interlinked via hydrogen bonds, resulting in the formation of 3D frameworks. There are small channels in 1 and 2 and two kinds of larger channels in 3 and 4, in which free bipy molecules residue. In 1 and 2, the Hiso2− anions act as tridentate ligands to link metal ions; in 3 and 4, the Hiso2− anions act as bidentate ligands and the metal ions are bridged by bipy." @default.
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- W2000574610 date "2004-09-01" @default.
- W2000574610 modified "2023-09-26" @default.
- W2000574610 title "Three-dimensional porous frameworks constructed by transition metal ions and isoorotic acid" @default.
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- W2000574610 doi "https://doi.org/10.1016/j.poly.2004.06.032" @default.
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