Matches in SemOpenAlex for { <https://semopenalex.org/work/W2000574656> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2000574656 endingPage "14773" @default.
- W2000574656 startingPage "14772" @default.
- W2000574656 abstract "We report a new class of bench-stable compounds that contain seemingly incompatible functional groups: an aldehyde and an unprotected secondary amine. The thermodynamic driving force to undergo condensation between these two functionalities is offset by a high barrier imposed on this process by the aziridine ring strain. The resulting amino aldehydes exist as dimers and in the solid state. They are stable to epimerization and contain two orthogonal reaction centers, namely, an amine/aziridine and an aldehyde. Their ability to act as linchpins has been evaluated in complex heterocycle synthesis. For instance, pentacyclic frameworks can be made in one simple operation using N-benzyltryptamine as the reaction partner. Construction of other molecular skeletons with minimal use of protecting group manipulations should be feasible." @default.
- W2000574656 created "2016-06-24" @default.
- W2000574656 creator A5049870216 @default.
- W2000574656 creator A5081408580 @default.
- W2000574656 date "2006-10-27" @default.
- W2000574656 modified "2023-10-15" @default.
- W2000574656 title "Readily Available Unprotected Amino Aldehydes" @default.
- W2000574656 cites W1540478558 @default.
- W2000574656 cites W2005646718 @default.
- W2000574656 cites W2010528162 @default.
- W2000574656 cites W2014196024 @default.
- W2000574656 cites W2064447071 @default.
- W2000574656 cites W2082452960 @default.
- W2000574656 cites W2083883361 @default.
- W2000574656 cites W2095140954 @default.
- W2000574656 cites W2950685256 @default.
- W2000574656 cites W562148525 @default.
- W2000574656 doi "https://doi.org/10.1021/ja065898s" @default.
- W2000574656 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17105264" @default.
- W2000574656 hasPublicationYear "2006" @default.
- W2000574656 type Work @default.
- W2000574656 sameAs 2000574656 @default.
- W2000574656 citedByCount "94" @default.
- W2000574656 countsByYear W20005746562012 @default.
- W2000574656 countsByYear W20005746562013 @default.
- W2000574656 countsByYear W20005746562014 @default.
- W2000574656 countsByYear W20005746562015 @default.
- W2000574656 countsByYear W20005746562016 @default.
- W2000574656 countsByYear W20005746562017 @default.
- W2000574656 countsByYear W20005746562018 @default.
- W2000574656 countsByYear W20005746562019 @default.
- W2000574656 countsByYear W20005746562020 @default.
- W2000574656 countsByYear W20005746562021 @default.
- W2000574656 countsByYear W20005746562022 @default.
- W2000574656 countsByYear W20005746562023 @default.
- W2000574656 crossrefType "journal-article" @default.
- W2000574656 hasAuthorship W2000574656A5049870216 @default.
- W2000574656 hasAuthorship W2000574656A5081408580 @default.
- W2000574656 hasConcept C131779359 @default.
- W2000574656 hasConcept C161790260 @default.
- W2000574656 hasConcept C178790620 @default.
- W2000574656 hasConcept C185592680 @default.
- W2000574656 hasConcept C203130289 @default.
- W2000574656 hasConcept C21951064 @default.
- W2000574656 hasConcept C2778544067 @default.
- W2000574656 hasConcept C2779825165 @default.
- W2000574656 hasConcept C2780378348 @default.
- W2000574656 hasConcept C515207424 @default.
- W2000574656 hasConcept C55493867 @default.
- W2000574656 hasConceptScore W2000574656C131779359 @default.
- W2000574656 hasConceptScore W2000574656C161790260 @default.
- W2000574656 hasConceptScore W2000574656C178790620 @default.
- W2000574656 hasConceptScore W2000574656C185592680 @default.
- W2000574656 hasConceptScore W2000574656C203130289 @default.
- W2000574656 hasConceptScore W2000574656C21951064 @default.
- W2000574656 hasConceptScore W2000574656C2778544067 @default.
- W2000574656 hasConceptScore W2000574656C2779825165 @default.
- W2000574656 hasConceptScore W2000574656C2780378348 @default.
- W2000574656 hasConceptScore W2000574656C515207424 @default.
- W2000574656 hasConceptScore W2000574656C55493867 @default.
- W2000574656 hasIssue "46" @default.
- W2000574656 hasLocation W20005746561 @default.
- W2000574656 hasLocation W20005746562 @default.
- W2000574656 hasOpenAccess W2000574656 @default.
- W2000574656 hasPrimaryLocation W20005746561 @default.
- W2000574656 hasRelatedWork W2010821211 @default.
- W2000574656 hasRelatedWork W2040620122 @default.
- W2000574656 hasRelatedWork W2081929173 @default.
- W2000574656 hasRelatedWork W2087846132 @default.
- W2000574656 hasRelatedWork W2345897290 @default.
- W2000574656 hasRelatedWork W2614576422 @default.
- W2000574656 hasRelatedWork W2915613132 @default.
- W2000574656 hasRelatedWork W2951245761 @default.
- W2000574656 hasRelatedWork W4206636524 @default.
- W2000574656 hasRelatedWork W74890541 @default.
- W2000574656 hasVolume "128" @default.
- W2000574656 isParatext "false" @default.
- W2000574656 isRetracted "false" @default.
- W2000574656 magId "2000574656" @default.
- W2000574656 workType "article" @default.